Gamma radiation-induced crosslinking of Ca2+ loaded poly(acrylic acid) and poly(ethylene glycol) diacrylate networks for polymer gel electrolytes

Gel electrolytes based on poly(acrylic acid) and poly(ethylene glycol)diacrylate (PAA-PEGDA-Ca2+) loaded with Ca2+ ions were successfully prepared using gamma irradiation. The use of radiation provides benefits, such as solventless preparation without byproducts. The obtained gel fraction, porosity,...

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Autores principales:	Chonlada Kanbua, Thanakrit Sirichaibhinyo, Thitirat Rattanawongwiboon, Pattra Lertsarawut, Prim Chanklinhorm, Sarute Ummartyotin
Formato:	article
Lenguaje:	EN
Publicado:	Elsevier 2022
Materias:	Gamma radiation induced crosslinking Poly(acrylic acid) Poly(ethylene glycol)diacrylate Gel polymer electrolyte Chemical engineering TP155-156
Acceso en línea:	https://doaj.org/article/bcbafae2b10642e58713bab8e7c10afa
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spelling	oai:doaj.org-article:bcbafae2b10642e58713bab8e7c10afa2021-11-28T04:28:52ZGamma radiation-induced crosslinking of Ca2+ loaded poly(acrylic acid) and poly(ethylene glycol) diacrylate networks for polymer gel electrolytes1026-918510.1016/j.sajce.2021.11.007https://doaj.org/article/bcbafae2b10642e58713bab8e7c10afa2022-01-01T00:00:00Zhttp://www.sciencedirect.com/science/article/pii/S1026918521000640https://doaj.org/toc/1026-9185Gel electrolytes based on poly(acrylic acid) and poly(ethylene glycol)diacrylate (PAA-PEGDA-Ca2+) loaded with Ca2+ ions were successfully prepared using gamma irradiation. The use of radiation provides benefits, such as solventless preparation without byproducts. The obtained gel fraction, porosity, and swelling ratio were in the range of 60–90%, 11–60%, and 4–12 g/g, respectively. Fourier transform infrared spectroscopy confirmed the successful crosslinking between PAA and PEGDA. Crystallinity remained unaffected by the incorporation of Ca2+ ions. The thermal decomposition of the gels started at 200°C. The morphology was reported to have a spherical shape. 0.36–0.74 wt.% of Ca2+ was uniformly distributed on the gel electrolyte surface. In the presence of Ca2+ ions, the ionic conductivity of the gels improved by ∼2 times, whereas compressive strength slightly dropped to the range of 6–12 MPa.Graphical abstract Image, graphical abstractChonlada KanbuaThanakrit SirichaibhinyoThitirat RattanawongwiboonPattra LertsarawutPrim ChanklinhormSarute UmmartyotinElsevierarticleGamma radiation induced crosslinkingPoly(acrylic acid)Poly(ethylene glycol)diacrylateGel polymer electrolyteChemical engineeringTP155-156ENSouth African Journal of Chemical Engineering, Vol 39, Iss , Pp 90-96 (2022)
institution	DOAJ
collection	DOAJ
language	EN
topic	Gamma radiation induced crosslinking Poly(acrylic acid) Poly(ethylene glycol)diacrylate Gel polymer electrolyte Chemical engineering TP155-156
spellingShingle	Gamma radiation induced crosslinking Poly(acrylic acid) Poly(ethylene glycol)diacrylate Gel polymer electrolyte Chemical engineering TP155-156 Chonlada Kanbua Thanakrit Sirichaibhinyo Thitirat Rattanawongwiboon Pattra Lertsarawut Prim Chanklinhorm Sarute Ummartyotin Gamma radiation-induced crosslinking of Ca2+ loaded poly(acrylic acid) and poly(ethylene glycol) diacrylate networks for polymer gel electrolytes
description	Gel electrolytes based on poly(acrylic acid) and poly(ethylene glycol)diacrylate (PAA-PEGDA-Ca2+) loaded with Ca2+ ions were successfully prepared using gamma irradiation. The use of radiation provides benefits, such as solventless preparation without byproducts. The obtained gel fraction, porosity, and swelling ratio were in the range of 60–90%, 11–60%, and 4–12 g/g, respectively. Fourier transform infrared spectroscopy confirmed the successful crosslinking between PAA and PEGDA. Crystallinity remained unaffected by the incorporation of Ca2+ ions. The thermal decomposition of the gels started at 200°C. The morphology was reported to have a spherical shape. 0.36–0.74 wt.% of Ca2+ was uniformly distributed on the gel electrolyte surface. In the presence of Ca2+ ions, the ionic conductivity of the gels improved by ∼2 times, whereas compressive strength slightly dropped to the range of 6–12 MPa.Graphical abstract Image, graphical abstract
format	article
author	Chonlada Kanbua Thanakrit Sirichaibhinyo Thitirat Rattanawongwiboon Pattra Lertsarawut Prim Chanklinhorm Sarute Ummartyotin
author_facet	Chonlada Kanbua Thanakrit Sirichaibhinyo Thitirat Rattanawongwiboon Pattra Lertsarawut Prim Chanklinhorm Sarute Ummartyotin
author_sort	Chonlada Kanbua
title	Gamma radiation-induced crosslinking of Ca2+ loaded poly(acrylic acid) and poly(ethylene glycol) diacrylate networks for polymer gel electrolytes
title_short	Gamma radiation-induced crosslinking of Ca2+ loaded poly(acrylic acid) and poly(ethylene glycol) diacrylate networks for polymer gel electrolytes
title_full	Gamma radiation-induced crosslinking of Ca2+ loaded poly(acrylic acid) and poly(ethylene glycol) diacrylate networks for polymer gel electrolytes
title_fullStr	Gamma radiation-induced crosslinking of Ca2+ loaded poly(acrylic acid) and poly(ethylene glycol) diacrylate networks for polymer gel electrolytes
title_full_unstemmed	Gamma radiation-induced crosslinking of Ca2+ loaded poly(acrylic acid) and poly(ethylene glycol) diacrylate networks for polymer gel electrolytes
title_sort	gamma radiation-induced crosslinking of ca2+ loaded poly(acrylic acid) and poly(ethylene glycol) diacrylate networks for polymer gel electrolytes
publisher	Elsevier
publishDate	2022
url	https://doaj.org/article/bcbafae2b10642e58713bab8e7c10afa
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Gamma radiation-induced crosslinking of Ca2+ loaded poly(acrylic acid) and poly(ethylene glycol) diacrylate networks for polymer gel electrolytes

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