Genesis of electron deficient Pt1(0) in PDMS-PEG aggregates

Synthesis of discrete reduced metal atoms weakly coordinated and stabilized in liquid media remains challenging. Here, the authors report the genesis of mononuclear electron deficient Pt1(0) in polydimethylsiloxane-polyethylene glycol aggregates, and its ultrahigh activity in olefin hydrosilylation...

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Autores principales:	Kairui Liu, Guangjin Hou, Jingbo Mao, Zhanwei Xu, Peifang Yan, Huixiang Li, Xinwen Guo, Shi Bai, Z. Conrad Zhang
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/bd0bbc25231a40bd827b6beb676365d8
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spelling	oai:doaj.org-article:bd0bbc25231a40bd827b6beb676365d82021-12-02T15:35:03ZGenesis of electron deficient Pt1(0) in PDMS-PEG aggregates10.1038/s41467-019-08804-y2041-1723https://doaj.org/article/bd0bbc25231a40bd827b6beb676365d82019-03-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-08804-yhttps://doaj.org/toc/2041-1723Synthesis of discrete reduced metal atoms weakly coordinated and stabilized in liquid media remains challenging. Here, the authors report the genesis of mononuclear electron deficient Pt1(0) in polydimethylsiloxane-polyethylene glycol aggregates, and its ultrahigh activity in olefin hydrosilylation with excellent terminal adducts selectivity.Kairui LiuGuangjin HouJingbo MaoZhanwei XuPeifang YanHuixiang LiXinwen GuoShi BaiZ. Conrad ZhangNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-8 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Kairui Liu Guangjin Hou Jingbo Mao Zhanwei Xu Peifang Yan Huixiang Li Xinwen Guo Shi Bai Z. Conrad Zhang Genesis of electron deficient Pt1(0) in PDMS-PEG aggregates
description	Synthesis of discrete reduced metal atoms weakly coordinated and stabilized in liquid media remains challenging. Here, the authors report the genesis of mononuclear electron deficient Pt1(0) in polydimethylsiloxane-polyethylene glycol aggregates, and its ultrahigh activity in olefin hydrosilylation with excellent terminal adducts selectivity.
format	article
author	Kairui Liu Guangjin Hou Jingbo Mao Zhanwei Xu Peifang Yan Huixiang Li Xinwen Guo Shi Bai Z. Conrad Zhang
author_facet	Kairui Liu Guangjin Hou Jingbo Mao Zhanwei Xu Peifang Yan Huixiang Li Xinwen Guo Shi Bai Z. Conrad Zhang
author_sort	Kairui Liu
title	Genesis of electron deficient Pt1(0) in PDMS-PEG aggregates
title_short	Genesis of electron deficient Pt1(0) in PDMS-PEG aggregates
title_full	Genesis of electron deficient Pt1(0) in PDMS-PEG aggregates
title_fullStr	Genesis of electron deficient Pt1(0) in PDMS-PEG aggregates
title_full_unstemmed	Genesis of electron deficient Pt1(0) in PDMS-PEG aggregates
title_sort	genesis of electron deficient pt1(0) in pdms-peg aggregates
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/bd0bbc25231a40bd827b6beb676365d8
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Genesis of electron deficient Pt1(0) in PDMS-PEG aggregates

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