Stereoselective oxidative glycosylation of anomeric nucleophiles with alcohols and carboxylic acids

Glycosylation of partially protected sugars is usually limited by suboptimal regio- and stereo-selectivities. Here, the authors show a general oxidative glycosylation between anomeric stannanes with a nonprotected hydroxyl group and oxygen nucleophiles, additionally providing mechanistic insights in...

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Auteurs principaux:	Tianyi Yang, Feng Zhu, Maciej A. Walczak
Format:	article
Langue:	EN
Publié:	Nature Portfolio 2018
Sujets:	Science Q
Accès en ligne:	https://doaj.org/article/bd44fa52016a458d892177d7d8de54c4
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id	oai:doaj.org-article:bd44fa52016a458d892177d7d8de54c4
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spelling	oai:doaj.org-article:bd44fa52016a458d892177d7d8de54c42021-12-02T16:49:48ZStereoselective oxidative glycosylation of anomeric nucleophiles with alcohols and carboxylic acids10.1038/s41467-018-06016-42041-1723https://doaj.org/article/bd44fa52016a458d892177d7d8de54c42018-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-06016-4https://doaj.org/toc/2041-1723Glycosylation of partially protected sugars is usually limited by suboptimal regio- and stereo-selectivities. Here, the authors show a general oxidative glycosylation between anomeric stannanes with a nonprotected hydroxyl group and oxygen nucleophiles, additionally providing mechanistic insights into the origin of selectivity.Tianyi YangFeng ZhuMaciej A. WalczakNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-9 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Tianyi Yang Feng Zhu Maciej A. Walczak Stereoselective oxidative glycosylation of anomeric nucleophiles with alcohols and carboxylic acids
description	Glycosylation of partially protected sugars is usually limited by suboptimal regio- and stereo-selectivities. Here, the authors show a general oxidative glycosylation between anomeric stannanes with a nonprotected hydroxyl group and oxygen nucleophiles, additionally providing mechanistic insights into the origin of selectivity.
format	article
author	Tianyi Yang Feng Zhu Maciej A. Walczak
author_facet	Tianyi Yang Feng Zhu Maciej A. Walczak
author_sort	Tianyi Yang
title	Stereoselective oxidative glycosylation of anomeric nucleophiles with alcohols and carboxylic acids
title_short	Stereoselective oxidative glycosylation of anomeric nucleophiles with alcohols and carboxylic acids
title_full	Stereoselective oxidative glycosylation of anomeric nucleophiles with alcohols and carboxylic acids
title_fullStr	Stereoselective oxidative glycosylation of anomeric nucleophiles with alcohols and carboxylic acids
title_full_unstemmed	Stereoselective oxidative glycosylation of anomeric nucleophiles with alcohols and carboxylic acids
title_sort	stereoselective oxidative glycosylation of anomeric nucleophiles with alcohols and carboxylic acids
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/bd44fa52016a458d892177d7d8de54c4
work_keys_str_mv	AT tianyiyang stereoselectiveoxidativeglycosylationofanomericnucleophileswithalcoholsandcarboxylicacids AT fengzhu stereoselectiveoxidativeglycosylationofanomericnucleophileswithalcoholsandcarboxylicacids AT maciejawalczak stereoselectiveoxidativeglycosylationofanomericnucleophileswithalcoholsandcarboxylicacids
_version_	1718383237152112640

Stereoselective oxidative glycosylation of anomeric nucleophiles with alcohols and carboxylic acids

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