Photo-induced catalytic halopyridylation of alkenes

The Mizoroki–Heck reaction and its reductive analogue are staples of organic synthesis, but the ensuing products often lack a chemical handle for further transformation. Here the authors present a method to add a heterocycle and transformable halide across a double bond via iridium photocatalysis.

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Autores principales: Shi-Yu Guo, Fan Yang, Ting-Ting Song, Yu-Qing Guan, Xiang-Ting Min, Ding-Wei Ji, Yan-Cheng Hu, Qing-An Chen
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/bd78ed914f094935accf9118a41ebd2d
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spelling oai:doaj.org-article:bd78ed914f094935accf9118a41ebd2d2021-11-14T12:36:25ZPhoto-induced catalytic halopyridylation of alkenes10.1038/s41467-021-26857-w2041-1723https://doaj.org/article/bd78ed914f094935accf9118a41ebd2d2021-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-26857-whttps://doaj.org/toc/2041-1723The Mizoroki–Heck reaction and its reductive analogue are staples of organic synthesis, but the ensuing products often lack a chemical handle for further transformation. Here the authors present a method to add a heterocycle and transformable halide across a double bond via iridium photocatalysis.Shi-Yu GuoFan YangTing-Ting SongYu-Qing GuanXiang-Ting MinDing-Wei JiYan-Cheng HuQing-An ChenNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-9 (2021)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Shi-Yu Guo
Fan Yang
Ting-Ting Song
Yu-Qing Guan
Xiang-Ting Min
Ding-Wei Ji
Yan-Cheng Hu
Qing-An Chen
Photo-induced catalytic halopyridylation of alkenes
description The Mizoroki–Heck reaction and its reductive analogue are staples of organic synthesis, but the ensuing products often lack a chemical handle for further transformation. Here the authors present a method to add a heterocycle and transformable halide across a double bond via iridium photocatalysis.
format article
author Shi-Yu Guo
Fan Yang
Ting-Ting Song
Yu-Qing Guan
Xiang-Ting Min
Ding-Wei Ji
Yan-Cheng Hu
Qing-An Chen
author_facet Shi-Yu Guo
Fan Yang
Ting-Ting Song
Yu-Qing Guan
Xiang-Ting Min
Ding-Wei Ji
Yan-Cheng Hu
Qing-An Chen
author_sort Shi-Yu Guo
title Photo-induced catalytic halopyridylation of alkenes
title_short Photo-induced catalytic halopyridylation of alkenes
title_full Photo-induced catalytic halopyridylation of alkenes
title_fullStr Photo-induced catalytic halopyridylation of alkenes
title_full_unstemmed Photo-induced catalytic halopyridylation of alkenes
title_sort photo-induced catalytic halopyridylation of alkenes
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/bd78ed914f094935accf9118a41ebd2d
work_keys_str_mv AT shiyuguo photoinducedcatalytichalopyridylationofalkenes
AT fanyang photoinducedcatalytichalopyridylationofalkenes
AT tingtingsong photoinducedcatalytichalopyridylationofalkenes
AT yuqingguan photoinducedcatalytichalopyridylationofalkenes
AT xiangtingmin photoinducedcatalytichalopyridylationofalkenes
AT dingweiji photoinducedcatalytichalopyridylationofalkenes
AT yanchenghu photoinducedcatalytichalopyridylationofalkenes
AT qinganchen photoinducedcatalytichalopyridylationofalkenes
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