DEARYLATION IN THE INTERACTIONS BETWEEN (Et3NH)HC2O4 OR (Et3NH)2C2O4 AND SnPh3Cl: INFRARED STUDY

Five new oxalato, hydrogenoxalato and hydrogenocarbonato adducts (three) and complexes (two) obtained on allowing (Et3NH)HC2O4 or (Et3NH)2C2O4 to react with SnPh3Cl have been studied by infrared spectroscopy, then discrete structures suggested on the basis of spectroscopic data. The anions behave a...

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Autores principales:	GORGUI AWA SECK, LIBASSE DIOP, ABOUBACARY SENE
Formato:	article
Lenguaje:	EN
Publicado:	Alma Mater Publishing House "Vasile Alecsandri" University of Bacau 2017
Materias:	discrete structures hydrogen bonds IR technic lattice benzene molecules monochelating oxoanions octahedral environments Technology T Engineering (General). Civil engineering (General) TA1-2040
Acceso en línea:	https://doaj.org/article/be8c58b1b1a2416ebc011838ac101137
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spelling	oai:doaj.org-article:be8c58b1b1a2416ebc011838ac1011372021-12-02T19:50:29ZDEARYLATION IN THE INTERACTIONS BETWEEN (Et3NH)HC2O4 OR (Et3NH)2C2O4 AND SnPh3Cl: INFRARED STUDY10.29081/jesr.v23i2.842068-75592344-4932https://doaj.org/article/be8c58b1b1a2416ebc011838ac1011372017-06-01T00:00:00Zhttp://www.jesr.ub.ro/1/article/view/84https://doaj.org/toc/2068-7559https://doaj.org/toc/2344-4932 Five new oxalato, hydrogenoxalato and hydrogenocarbonato adducts (three) and complexes (two) obtained on allowing (Et3NH)HC2O4 or (Et3NH)2C2O4 to react with SnPh3Cl have been studied by infrared spectroscopy, then discrete structures suggested on the basis of spectroscopic data. The anions behave as monochelating ligands, the environments around the metallic centres being octahedral. In two of the compounds, the benzene molecules obtained in situ are lattice. In all these structures when considering the cation involved in extra hydrogen bonds, a supramolecular architecture may be obtained. GORGUI AWA SECKLIBASSE DIOPABOUBACARY SENEAlma Mater Publishing House "Vasile Alecsandri" University of Bacauarticlediscrete structureshydrogen bondsIR techniclattice benzene moleculesmonochelating oxoanionsoctahedral environmentsTechnologyTEngineering (General). Civil engineering (General)TA1-2040ENJournal of Engineering Studies and Research, Vol 23, Iss 2 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	discrete structures hydrogen bonds IR technic lattice benzene molecules monochelating oxoanions octahedral environments Technology T Engineering (General). Civil engineering (General) TA1-2040
spellingShingle	discrete structures hydrogen bonds IR technic lattice benzene molecules monochelating oxoanions octahedral environments Technology T Engineering (General). Civil engineering (General) TA1-2040 GORGUI AWA SECK LIBASSE DIOP ABOUBACARY SENE DEARYLATION IN THE INTERACTIONS BETWEEN (Et3NH)HC2O4 OR (Et3NH)2C2O4 AND SnPh3Cl: INFRARED STUDY
description	Five new oxalato, hydrogenoxalato and hydrogenocarbonato adducts (three) and complexes (two) obtained on allowing (Et3NH)HC2O4 or (Et3NH)2C2O4 to react with SnPh3Cl have been studied by infrared spectroscopy, then discrete structures suggested on the basis of spectroscopic data. The anions behave as monochelating ligands, the environments around the metallic centres being octahedral. In two of the compounds, the benzene molecules obtained in situ are lattice. In all these structures when considering the cation involved in extra hydrogen bonds, a supramolecular architecture may be obtained.
format	article
author	GORGUI AWA SECK LIBASSE DIOP ABOUBACARY SENE
author_facet	GORGUI AWA SECK LIBASSE DIOP ABOUBACARY SENE
author_sort	GORGUI AWA SECK
title	DEARYLATION IN THE INTERACTIONS BETWEEN (Et3NH)HC2O4 OR (Et3NH)2C2O4 AND SnPh3Cl: INFRARED STUDY
title_short	DEARYLATION IN THE INTERACTIONS BETWEEN (Et3NH)HC2O4 OR (Et3NH)2C2O4 AND SnPh3Cl: INFRARED STUDY
title_full	DEARYLATION IN THE INTERACTIONS BETWEEN (Et3NH)HC2O4 OR (Et3NH)2C2O4 AND SnPh3Cl: INFRARED STUDY
title_fullStr	DEARYLATION IN THE INTERACTIONS BETWEEN (Et3NH)HC2O4 OR (Et3NH)2C2O4 AND SnPh3Cl: INFRARED STUDY
title_full_unstemmed	DEARYLATION IN THE INTERACTIONS BETWEEN (Et3NH)HC2O4 OR (Et3NH)2C2O4 AND SnPh3Cl: INFRARED STUDY
title_sort	dearylation in the interactions between (et3nh)hc2o4 or (et3nh)2c2o4 and snph3cl: infrared study
publisher	Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
publishDate	2017
url	https://doaj.org/article/be8c58b1b1a2416ebc011838ac101137
work_keys_str_mv	AT gorguiawaseck dearylationintheinteractionsbetweenet3nhhc2o4oret3nh2c2o4andsnph3clinfraredstudy AT libassediop dearylationintheinteractionsbetweenet3nhhc2o4oret3nh2c2o4andsnph3clinfraredstudy AT aboubacarysene dearylationintheinteractionsbetweenet3nhhc2o4oret3nh2c2o4andsnph3clinfraredstudy
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DEARYLATION IN THE INTERACTIONS BETWEEN (Et3NH)HC2O4 OR (Et3NH)2C2O4 AND SnPh3Cl: INFRARED STUDY

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