Polymerization driven monomer passage through monolayer chemical vapour deposition graphene

Translocation of larger molecules through graphene holds potential for molecular sieving, however it is rarely observed. Here, the authors show the radical polymerization of vinyl monomers via their translocation through a single layer graphene to a monolayer initiator and additionally study the mon...

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Autores principales: Tao Zhang, Zhongquan Liao, Leonardo Medrano Sandonas, Arezoo Dianat, Xiaoling Liu, Peng Xiao, Ihsan Amin, Rafael Gutierrez, Tao Chen, Ehrenfried Zschech, Gianaurelio Cuniberti, Rainer Jordan
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2018
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Acceso en línea:https://doaj.org/article/beec226f17624adbb5c2b04c4aae31a9
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Sumario:Translocation of larger molecules through graphene holds potential for molecular sieving, however it is rarely observed. Here, the authors show the radical polymerization of vinyl monomers via their translocation through a single layer graphene to a monolayer initiator and additionally study the monomer-graphene interactions.