An ultra-low thiourea catalyzed strain-release glycosylation and a multicatalytic diversification strategy
Non-covalent glycosyl donor activation often requires high organocatalyst loadings. Here, the authors demonstrate that strain-release glycosylations can take place at very low thiourea catalyst loadings. In addition, the authors developed a one-pot multicatalytic strategy that can diversify glycosid...
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Nature Portfolio
2018
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oai:doaj.org-article:bf2fd9e1731b4649aed90bc2f3e92b752021-12-02T15:34:43ZAn ultra-low thiourea catalyzed strain-release glycosylation and a multicatalytic diversification strategy10.1038/s41467-018-06329-42041-1723https://doaj.org/article/bf2fd9e1731b4649aed90bc2f3e92b752018-10-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-06329-4https://doaj.org/toc/2041-1723Non-covalent glycosyl donor activation often requires high organocatalyst loadings. Here, the authors demonstrate that strain-release glycosylations can take place at very low thiourea catalyst loadings. In addition, the authors developed a one-pot multicatalytic strategy that can diversify glycosides rapidly.Chunfa XuCharles C. J. LohNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-12 (2018) |
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Science Q Chunfa Xu Charles C. J. Loh An ultra-low thiourea catalyzed strain-release glycosylation and a multicatalytic diversification strategy |
description |
Non-covalent glycosyl donor activation often requires high organocatalyst loadings. Here, the authors demonstrate that strain-release glycosylations can take place at very low thiourea catalyst loadings. In addition, the authors developed a one-pot multicatalytic strategy that can diversify glycosides rapidly. |
format |
article |
author |
Chunfa Xu Charles C. J. Loh |
author_facet |
Chunfa Xu Charles C. J. Loh |
author_sort |
Chunfa Xu |
title |
An ultra-low thiourea catalyzed strain-release glycosylation and a multicatalytic diversification strategy |
title_short |
An ultra-low thiourea catalyzed strain-release glycosylation and a multicatalytic diversification strategy |
title_full |
An ultra-low thiourea catalyzed strain-release glycosylation and a multicatalytic diversification strategy |
title_fullStr |
An ultra-low thiourea catalyzed strain-release glycosylation and a multicatalytic diversification strategy |
title_full_unstemmed |
An ultra-low thiourea catalyzed strain-release glycosylation and a multicatalytic diversification strategy |
title_sort |
ultra-low thiourea catalyzed strain-release glycosylation and a multicatalytic diversification strategy |
publisher |
Nature Portfolio |
publishDate |
2018 |
url |
https://doaj.org/article/bf2fd9e1731b4649aed90bc2f3e92b75 |
work_keys_str_mv |
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