Dye-incorporated coordination polymers for direct photocatalytic trifluoromethylation of aromatics at metabolically susceptible positions

Direct trifluoromethylation of unactivated aromatic rings at metabolically susceptible positions is highly desirable in pharmaceutical fields. Here, the authors report a new approach for direct trifluoromethylation of unactivated aromatics by incorporating thiophenes into the backbone of triphenylam...

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Autores principales:	Tiexin Zhang, Xiangyang Guo, Yusheng Shi, Cheng He, Chunying Duan
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/bf76ba626bd5497ab5405f99e5c1b74c
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spelling	oai:doaj.org-article:bf76ba626bd5497ab5405f99e5c1b74c2021-12-02T15:34:50ZDye-incorporated coordination polymers for direct photocatalytic trifluoromethylation of aromatics at metabolically susceptible positions10.1038/s41467-018-05919-62041-1723https://doaj.org/article/bf76ba626bd5497ab5405f99e5c1b74c2018-10-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-05919-6https://doaj.org/toc/2041-1723Direct trifluoromethylation of unactivated aromatic rings at metabolically susceptible positions is highly desirable in pharmaceutical fields. Here, the authors report a new approach for direct trifluoromethylation of unactivated aromatics by incorporating thiophenes into the backbone of triphenylamine-based ligand.Tiexin ZhangXiangyang GuoYusheng ShiCheng HeChunying DuanNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-9 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Tiexin Zhang Xiangyang Guo Yusheng Shi Cheng He Chunying Duan Dye-incorporated coordination polymers for direct photocatalytic trifluoromethylation of aromatics at metabolically susceptible positions
description	Direct trifluoromethylation of unactivated aromatic rings at metabolically susceptible positions is highly desirable in pharmaceutical fields. Here, the authors report a new approach for direct trifluoromethylation of unactivated aromatics by incorporating thiophenes into the backbone of triphenylamine-based ligand.
format	article
author	Tiexin Zhang Xiangyang Guo Yusheng Shi Cheng He Chunying Duan
author_facet	Tiexin Zhang Xiangyang Guo Yusheng Shi Cheng He Chunying Duan
author_sort	Tiexin Zhang
title	Dye-incorporated coordination polymers for direct photocatalytic trifluoromethylation of aromatics at metabolically susceptible positions
title_short	Dye-incorporated coordination polymers for direct photocatalytic trifluoromethylation of aromatics at metabolically susceptible positions
title_full	Dye-incorporated coordination polymers for direct photocatalytic trifluoromethylation of aromatics at metabolically susceptible positions
title_fullStr	Dye-incorporated coordination polymers for direct photocatalytic trifluoromethylation of aromatics at metabolically susceptible positions
title_full_unstemmed	Dye-incorporated coordination polymers for direct photocatalytic trifluoromethylation of aromatics at metabolically susceptible positions
title_sort	dye-incorporated coordination polymers for direct photocatalytic trifluoromethylation of aromatics at metabolically susceptible positions
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/bf76ba626bd5497ab5405f99e5c1b74c
work_keys_str_mv	AT tiexinzhang dyeincorporatedcoordinationpolymersfordirectphotocatalytictrifluoromethylationofaromaticsatmetabolicallysusceptiblepositions AT xiangyangguo dyeincorporatedcoordinationpolymersfordirectphotocatalytictrifluoromethylationofaromaticsatmetabolicallysusceptiblepositions AT yushengshi dyeincorporatedcoordinationpolymersfordirectphotocatalytictrifluoromethylationofaromaticsatmetabolicallysusceptiblepositions AT chenghe dyeincorporatedcoordinationpolymersfordirectphotocatalytictrifluoromethylationofaromaticsatmetabolicallysusceptiblepositions AT chunyingduan dyeincorporatedcoordinationpolymersfordirectphotocatalytictrifluoromethylationofaromaticsatmetabolicallysusceptiblepositions
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Dye-incorporated coordination polymers for direct photocatalytic trifluoromethylation of aromatics at metabolically susceptible positions

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