Precise Control of Nanoscale Interface for Efficient Electrochemical Reactions

Control of the nanoscale interface leads to efficient electrochemical reactions and unique molecular behaviors. This paper reviews our recent investigations on understanding the unique property of the electrochemical reactions at nanostructured interfaces. We have focused on the control of chemical...

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Autores principales: Hiro MINAMIMOTO, Kei MURAKOSHI
Formato: article
Lenguaje:EN
JA
Publicado: The Electrochemical Society of Japan 2021
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Acceso en línea:https://doaj.org/article/c0137a2a1967411794e30e9195113b33
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spelling oai:doaj.org-article:c0137a2a1967411794e30e9195113b332021-11-05T00:17:27ZPrecise Control of Nanoscale Interface for Efficient Electrochemical Reactions2186-245110.5796/electrochemistry.21-00080https://doaj.org/article/c0137a2a1967411794e30e9195113b332021-11-01T00:00:00Zhttps://www.jstage.jst.go.jp/article/electrochemistry/89/6/89_21-00080/_html/-char/enhttps://doaj.org/toc/2186-2451Control of the nanoscale interface leads to efficient electrochemical reactions and unique molecular behaviors. This paper reviews our recent investigations on understanding the unique property of the electrochemical reactions at nanostructured interfaces. We have focused on the control of chemical reactions in the vicinity of metal nanostructures to condense the energy perturbations of electrons, ions, and photons. We have established an electrochemical nanostructure control method to achieve ultimate energy condensation. In addition, we have revealed the unique molecular behaviors induced by the strong interaction between the target molecules and the nanostructured electrode, originating from the hybridization of the electronic states showing collective excitation modes especially under the light illumination. Furthermore, we have attempted to efficiently control the electrochemical reactions and observe the unique reaction selectivity on the nanostructured electrodes. Through these investigations, we have proposed advantages for the control of nanostructured interfaces to overcome the current limitation of electrochemical reactions.Hiro MINAMIMOTOKei MURAKOSHIThe Electrochemical Society of Japanarticlelocalized surface plasmon resonanceplasmon-induced electron transferelectrochemical surface-enhanced raman scatteringhydrogen evolution reactionTechnologyTPhysical and theoretical chemistryQD450-801ENJAElectrochemistry, Vol 89, Iss 6, Pp 525-535 (2021)
institution DOAJ
collection DOAJ
language EN
JA
topic localized surface plasmon resonance
plasmon-induced electron transfer
electrochemical surface-enhanced raman scattering
hydrogen evolution reaction
Technology
T
Physical and theoretical chemistry
QD450-801
spellingShingle localized surface plasmon resonance
plasmon-induced electron transfer
electrochemical surface-enhanced raman scattering
hydrogen evolution reaction
Technology
T
Physical and theoretical chemistry
QD450-801
Hiro MINAMIMOTO
Kei MURAKOSHI
Precise Control of Nanoscale Interface for Efficient Electrochemical Reactions
description Control of the nanoscale interface leads to efficient electrochemical reactions and unique molecular behaviors. This paper reviews our recent investigations on understanding the unique property of the electrochemical reactions at nanostructured interfaces. We have focused on the control of chemical reactions in the vicinity of metal nanostructures to condense the energy perturbations of electrons, ions, and photons. We have established an electrochemical nanostructure control method to achieve ultimate energy condensation. In addition, we have revealed the unique molecular behaviors induced by the strong interaction between the target molecules and the nanostructured electrode, originating from the hybridization of the electronic states showing collective excitation modes especially under the light illumination. Furthermore, we have attempted to efficiently control the electrochemical reactions and observe the unique reaction selectivity on the nanostructured electrodes. Through these investigations, we have proposed advantages for the control of nanostructured interfaces to overcome the current limitation of electrochemical reactions.
format article
author Hiro MINAMIMOTO
Kei MURAKOSHI
author_facet Hiro MINAMIMOTO
Kei MURAKOSHI
author_sort Hiro MINAMIMOTO
title Precise Control of Nanoscale Interface for Efficient Electrochemical Reactions
title_short Precise Control of Nanoscale Interface for Efficient Electrochemical Reactions
title_full Precise Control of Nanoscale Interface for Efficient Electrochemical Reactions
title_fullStr Precise Control of Nanoscale Interface for Efficient Electrochemical Reactions
title_full_unstemmed Precise Control of Nanoscale Interface for Efficient Electrochemical Reactions
title_sort precise control of nanoscale interface for efficient electrochemical reactions
publisher The Electrochemical Society of Japan
publishDate 2021
url https://doaj.org/article/c0137a2a1967411794e30e9195113b33
work_keys_str_mv AT hirominamimoto precisecontrolofnanoscaleinterfaceforefficientelectrochemicalreactions
AT keimurakoshi precisecontrolofnanoscaleinterfaceforefficientelectrochemicalreactions
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