Chirality recognition of winding vine-shaped heterobiaryls with molecular asymmetry. Kinetic and dynamic kinetic resolution by Shi’s asymmetric epoxidation
Abstract The chirality of winding vine-shaped heterobiaryls with molecular asymmetry is recognized by a sugar-based chiral oxidant. Kinetic resolution of (±)-bisbenzoimidazole bearing an olefin moiety takes place with Shi’s asymmetric epoxidation to observe krel value up to ca. 35 affording the corr...
Guardado en:
Autores principales: | Kazuki Maruhashi, Yoichi Okayama, Ryo Inoue, Shiomi Ashida, Yuka Toyomori, Kentaro Okano, Atsunori Mori |
---|---|
Formato: | article |
Lenguaje: | EN |
Publicado: |
Nature Portfolio
2018
|
Materias: | |
Acceso en línea: | https://doaj.org/article/c04e0dd87eb9419b8009fd40035080e4 |
Etiquetas: |
Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
|
Ejemplares similares
-
Kinetic asymmetry allows macromolecular catalysts to drive an information ratchet
por: R. Dean Astumian
Publicado: (2019) - Kinetics and catalysis
-
Kinetic Asymmetry During a Repetitive Tuck Jump Task in Athletes with a History of Anterior Cruciate Ligament Reconstruction
por: Adam W. VanZile, et al.
Publicado: (2021) -
Kinetic Study of Esterification Reaction
por: Haider A. Al-Jendeel, et al.
Publicado: (2010) - International journal of chemical kinetics