Oxidation of difluorocarbene and subsequent trifluoromethoxylation

Difluorocarbene is a versatile and efficient intermediate for fluorine incorporation. Here, the authors show that difluorocarbene can be oxidized to carbonyl fluoride and this process is confirmed in 18O-trifluoromethoxylation reactions, by observation of AgOCF3 species and theory.

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Detalles Bibliográficos
Autores principales: Jiao Yu, Jin-Hong Lin, Donghai Yu, Ruobing Du, Ji-Chang Xiao
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/c07c235c8ba24b71b97241c47c4dd27f
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Descripción
Sumario:Difluorocarbene is a versatile and efficient intermediate for fluorine incorporation. Here, the authors show that difluorocarbene can be oxidized to carbonyl fluoride and this process is confirmed in 18O-trifluoromethoxylation reactions, by observation of AgOCF3 species and theory.