Oxidation of difluorocarbene and subsequent trifluoromethoxylation

Difluorocarbene is a versatile and efficient intermediate for fluorine incorporation. Here, the authors show that difluorocarbene can be oxidized to carbonyl fluoride and this process is confirmed in 18O-trifluoromethoxylation reactions, by observation of AgOCF3 species and theory.

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Autores principales:	Jiao Yu, Jin-Hong Lin, Donghai Yu, Ruobing Du, Ji-Chang Xiao
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/c07c235c8ba24b71b97241c47c4dd27f
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spelling	oai:doaj.org-article:c07c235c8ba24b71b97241c47c4dd27f2021-12-02T15:35:35ZOxidation of difluorocarbene and subsequent trifluoromethoxylation10.1038/s41467-019-13359-z2041-1723https://doaj.org/article/c07c235c8ba24b71b97241c47c4dd27f2019-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-13359-zhttps://doaj.org/toc/2041-1723Difluorocarbene is a versatile and efficient intermediate for fluorine incorporation. Here, the authors show that difluorocarbene can be oxidized to carbonyl fluoride and this process is confirmed in 18O-trifluoromethoxylation reactions, by observation of AgOCF3 species and theory.Jiao YuJin-Hong LinDonghai YuRuobing DuJi-Chang XiaoNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-8 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Jiao Yu Jin-Hong Lin Donghai Yu Ruobing Du Ji-Chang Xiao Oxidation of difluorocarbene and subsequent trifluoromethoxylation
description	Difluorocarbene is a versatile and efficient intermediate for fluorine incorporation. Here, the authors show that difluorocarbene can be oxidized to carbonyl fluoride and this process is confirmed in 18O-trifluoromethoxylation reactions, by observation of AgOCF3 species and theory.
format	article
author	Jiao Yu Jin-Hong Lin Donghai Yu Ruobing Du Ji-Chang Xiao
author_facet	Jiao Yu Jin-Hong Lin Donghai Yu Ruobing Du Ji-Chang Xiao
author_sort	Jiao Yu
title	Oxidation of difluorocarbene and subsequent trifluoromethoxylation
title_short	Oxidation of difluorocarbene and subsequent trifluoromethoxylation
title_full	Oxidation of difluorocarbene and subsequent trifluoromethoxylation
title_fullStr	Oxidation of difluorocarbene and subsequent trifluoromethoxylation
title_full_unstemmed	Oxidation of difluorocarbene and subsequent trifluoromethoxylation
title_sort	oxidation of difluorocarbene and subsequent trifluoromethoxylation
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/c07c235c8ba24b71b97241c47c4dd27f
work_keys_str_mv	AT jiaoyu oxidationofdifluorocarbeneandsubsequenttrifluoromethoxylation AT jinhonglin oxidationofdifluorocarbeneandsubsequenttrifluoromethoxylation AT donghaiyu oxidationofdifluorocarbeneandsubsequenttrifluoromethoxylation AT ruobingdu oxidationofdifluorocarbeneandsubsequenttrifluoromethoxylation AT jichangxiao oxidationofdifluorocarbeneandsubsequenttrifluoromethoxylation
_version_	1718386559396347904

Oxidation of difluorocarbene and subsequent trifluoromethoxylation

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