Oxidation of difluorocarbene and subsequent trifluoromethoxylation

Oxidation of difluorocarbene and subsequent trifluoromethoxylation

Difluorocarbene is a versatile and efficient intermediate for fluorine incorporation. Here, the authors show that difluorocarbene can be oxidized to carbonyl fluoride and this process is confirmed in 18O-trifluoromethoxylation reactions, by observation of AgOCF3 species and theory.

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Main Authors: Jiao Yu, Jin-Hong Lin, Donghai Yu, Ruobing Du, Ji-Chang Xiao
Format: article
Language:EN
Published: Nature Portfolio 2019
Subjects:
Science
Q
Online Access:https://doaj.org/article/c07c235c8ba24b71b97241c47c4dd27f
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spelling oai:doaj.org-article:c07c235c8ba24b71b97241c47c4dd27f2021-12-02T15:35:35ZOxidation of difluorocarbene and subsequent trifluoromethoxylation10.1038/s41467-019-13359-z2041-1723https://doaj.org/article/c07c235c8ba24b71b97241c47c4dd27f2019-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-13359-zhttps://doaj.org/toc/2041-1723Difluorocarbene is a versatile and efficient intermediate for fluorine incorporation. Here, the authors show that difluorocarbene can be oxidized to carbonyl fluoride and this process is confirmed in 18O-trifluoromethoxylation reactions, by observation of AgOCF3 species and theory.Jiao YuJin-Hong LinDonghai YuRuobing DuJi-Chang XiaoNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-8 (2019)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Jiao Yu
Jin-Hong Lin
Donghai Yu
Ruobing Du
Ji-Chang Xiao
Oxidation of difluorocarbene and subsequent trifluoromethoxylation
description Difluorocarbene is a versatile and efficient intermediate for fluorine incorporation. Here, the authors show that difluorocarbene can be oxidized to carbonyl fluoride and this process is confirmed in 18O-trifluoromethoxylation reactions, by observation of AgOCF3 species and theory.
format article
author Jiao Yu
Jin-Hong Lin
Donghai Yu
Ruobing Du
Ji-Chang Xiao
author_facet Jiao Yu
Jin-Hong Lin
Donghai Yu
Ruobing Du
Ji-Chang Xiao
author_sort Jiao Yu
title Oxidation of difluorocarbene and subsequent trifluoromethoxylation
title_short Oxidation of difluorocarbene and subsequent trifluoromethoxylation
title_full Oxidation of difluorocarbene and subsequent trifluoromethoxylation
title_fullStr Oxidation of difluorocarbene and subsequent trifluoromethoxylation
title_full_unstemmed Oxidation of difluorocarbene and subsequent trifluoromethoxylation
title_sort oxidation of difluorocarbene and subsequent trifluoromethoxylation
publisher Nature Portfolio
publishDate 2019
url https://doaj.org/article/c07c235c8ba24b71b97241c47c4dd27f
work_keys_str_mv AT jiaoyu oxidationofdifluorocarbeneandsubsequenttrifluoromethoxylation
AT jinhonglin oxidationofdifluorocarbeneandsubsequenttrifluoromethoxylation
AT donghaiyu oxidationofdifluorocarbeneandsubsequenttrifluoromethoxylation
AT ruobingdu oxidationofdifluorocarbeneandsubsequenttrifluoromethoxylation
AT jichangxiao oxidationofdifluorocarbeneandsubsequenttrifluoromethoxylation
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