Oxidation of difluorocarbene and subsequent trifluoromethoxylation
Difluorocarbene is a versatile and efficient intermediate for fluorine incorporation. Here, the authors show that difluorocarbene can be oxidized to carbonyl fluoride and this process is confirmed in 18O-trifluoromethoxylation reactions, by observation of AgOCF3 species and theory.
Guardado en:
Autores principales: | Jiao Yu, Jin-Hong Lin, Donghai Yu, Ruobing Du, Ji-Chang Xiao |
---|---|
Formato: | article |
Lenguaje: | EN |
Publicado: |
Nature Portfolio
2019
|
Materias: | |
Acceso en línea: | https://doaj.org/article/c07c235c8ba24b71b97241c47c4dd27f |
Etiquetas: |
Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
|
Ejemplares similares
-
Difluorocarbene enables to access 2-fluoroindoles from ortho-vinylanilines
por: Jianke Su, et al.
Publicado: (2021) -
Nucleophilic trifluoromethoxylation of alkyl halides without silver
por: Yan Li, et al.
Publicado: (2020) -
Ring-opening functionalizations of unstrained cyclic amines enabled by difluorocarbene transfer
por: Youyoung Kim, et al.
Publicado: (2020) -
Selective C-H trifluoromethoxylation of (hetero)arenes as limiting reagent
por: Zhijie Deng, et al.
Publicado: (2020) -
Twin birth changes DNA methylation of subsequent siblings
por: Shuai Li, et al.
Publicado: (2017)