Catalytic asymmetric Nakamura reaction by gold(I)/chiral N,Nʹ-dioxide-indium(III) or nickel(II) synergistic catalysis

Catalytic asymmetric Nakamura reaction by gold(I)/chiral N,Nʹ-dioxide-indium(III) or nickel(II) synergistic catalysis

Although enols and enolates addition to unactivated alkynes is used for carbon-carbon bond modification a catalytic asymmetric alkyne with 1,3-dicarbonyl compound has been elusive. Here, the authors achieve this using the synergistic activation of chiral N,N′-dioxide-indium(III) or nickel(II) Lewis...

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Autores principales: Xinyue Hu, Xiaoxue Tang, Xiying Zhang, Lili Lin, Xiaoming Feng
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/c0aa41cc7c1143b6bf4620373dab5bd5
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spelling oai:doaj.org-article:c0aa41cc7c1143b6bf4620373dab5bd52021-12-02T14:58:43ZCatalytic asymmetric Nakamura reaction by gold(I)/chiral N,Nʹ-dioxide-indium(III) or nickel(II) synergistic catalysis10.1038/s41467-021-23105-z2041-1723https://doaj.org/article/c0aa41cc7c1143b6bf4620373dab5bd52021-05-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-23105-zhttps://doaj.org/toc/2041-1723Although enols and enolates addition to unactivated alkynes is used for carbon-carbon bond modification a catalytic asymmetric alkyne with 1,3-dicarbonyl compound has been elusive. Here, the authors achieve this using the synergistic activation of chiral N,N′-dioxide-indium(III) or nickel(II) Lewis acid and achiral gold(I) π-acid.”Xinyue HuXiaoxue TangXiying ZhangLili LinXiaoming FengNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-10 (2021)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Xinyue Hu
Xiaoxue Tang
Xiying Zhang
Lili Lin
Xiaoming Feng
Catalytic asymmetric Nakamura reaction by gold(I)/chiral N,Nʹ-dioxide-indium(III) or nickel(II) synergistic catalysis
description Although enols and enolates addition to unactivated alkynes is used for carbon-carbon bond modification a catalytic asymmetric alkyne with 1,3-dicarbonyl compound has been elusive. Here, the authors achieve this using the synergistic activation of chiral N,N′-dioxide-indium(III) or nickel(II) Lewis acid and achiral gold(I) π-acid.”
format article
author Xinyue Hu
Xiaoxue Tang
Xiying Zhang
Lili Lin
Xiaoming Feng
author_facet Xinyue Hu
Xiaoxue Tang
Xiying Zhang
Lili Lin
Xiaoming Feng
author_sort Xinyue Hu
title Catalytic asymmetric Nakamura reaction by gold(I)/chiral N,Nʹ-dioxide-indium(III) or nickel(II) synergistic catalysis
title_short Catalytic asymmetric Nakamura reaction by gold(I)/chiral N,Nʹ-dioxide-indium(III) or nickel(II) synergistic catalysis
title_full Catalytic asymmetric Nakamura reaction by gold(I)/chiral N,Nʹ-dioxide-indium(III) or nickel(II) synergistic catalysis
title_fullStr Catalytic asymmetric Nakamura reaction by gold(I)/chiral N,Nʹ-dioxide-indium(III) or nickel(II) synergistic catalysis
title_full_unstemmed Catalytic asymmetric Nakamura reaction by gold(I)/chiral N,Nʹ-dioxide-indium(III) or nickel(II) synergistic catalysis
title_sort catalytic asymmetric nakamura reaction by gold(i)/chiral n,nʹ-dioxide-indium(iii) or nickel(ii) synergistic catalysis
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/c0aa41cc7c1143b6bf4620373dab5bd5
work_keys_str_mv AT xinyuehu catalyticasymmetricnakamurareactionbygoldichiralnnʹdioxideindiumiiiornickeliisynergisticcatalysis
AT xiaoxuetang catalyticasymmetricnakamurareactionbygoldichiralnnʹdioxideindiumiiiornickeliisynergisticcatalysis
AT xiyingzhang catalyticasymmetricnakamurareactionbygoldichiralnnʹdioxideindiumiiiornickeliisynergisticcatalysis
AT lililin catalyticasymmetricnakamurareactionbygoldichiralnnʹdioxideindiumiiiornickeliisynergisticcatalysis
AT xiaomingfeng catalyticasymmetricnakamurareactionbygoldichiralnnʹdioxideindiumiiiornickeliisynergisticcatalysis
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