Assessment of the release of metals from cigarette butts into the environment

Cigarette butts are known to contain toxic metals which pose a potential threat to the environment and human health. The seriousness of this threat is largely determined by the leachability of these toxic metals when the butts are exposed to aqueous solutions in the environment. The aims of this stu...

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Autores principales: Carla Roselli, Ivan Fagiolino, Donatella Desideri, Davide Sisti, Maria Assunta Meli
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Lenguaje:EN
Publicado: Public Library of Science (PLoS) 2021
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Acceso en línea:https://doaj.org/article/c0e6f24179344f349c0017a1e75589f8
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spelling oai:doaj.org-article:c0e6f24179344f349c0017a1e75589f82021-11-25T06:19:44ZAssessment of the release of metals from cigarette butts into the environment1932-6203https://doaj.org/article/c0e6f24179344f349c0017a1e75589f82021-01-01T00:00:00Zhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC8601425/?tool=EBIhttps://doaj.org/toc/1932-6203Cigarette butts are known to contain toxic metals which pose a potential threat to the environment and human health. The seriousness of this threat is largely determined by the leachability of these toxic metals when the butts are exposed to aqueous solutions in the environment. The aims of this study were to determine the presence and mobility of toxic and non-toxic elements found in discarded cigarette butts; to relate this mobility to two different contact situations with leaching liquids: tumbling and trampling (batch test) and percolation in a static position (column test); and finally, to verify possible variations in solubility by simulating different environmental systems. Five leachants with different pH values were used to simulate various environmental conditions The concentrations of the solubilized metals were determined by inductively coupled plasma-atomic emission spectrometry (ICP-AES) and inductively coupled plasma-mass spectrometry (ICP-MS). CH3COOH pH 2.5 showed the greatest capacity to dissolve many elements. On the contrary, weakly acidic or alkaline environments did not favor the leachability of the elements. The best extraction capacity of the column with respect to the batch is statistically significant (p <0.05) for the elements Al, Fe, Ni and Zn, while the batch for P, Si, S. Pb, Cd, As were not detectable in cigarette butts, while Hg had an average concentration of 0.0502 μg/g. However, Hg was < LOD in all different leachants.Carla RoselliIvan FagiolinoDonatella DesideriDavide SistiMaria Assunta MeliPublic Library of Science (PLoS)articleMedicineRScienceQENPLoS ONE, Vol 16, Iss 11 (2021)
institution DOAJ
collection DOAJ
language EN
topic Medicine
R
Science
Q
spellingShingle Medicine
R
Science
Q
Carla Roselli
Ivan Fagiolino
Donatella Desideri
Davide Sisti
Maria Assunta Meli
Assessment of the release of metals from cigarette butts into the environment
description Cigarette butts are known to contain toxic metals which pose a potential threat to the environment and human health. The seriousness of this threat is largely determined by the leachability of these toxic metals when the butts are exposed to aqueous solutions in the environment. The aims of this study were to determine the presence and mobility of toxic and non-toxic elements found in discarded cigarette butts; to relate this mobility to two different contact situations with leaching liquids: tumbling and trampling (batch test) and percolation in a static position (column test); and finally, to verify possible variations in solubility by simulating different environmental systems. Five leachants with different pH values were used to simulate various environmental conditions The concentrations of the solubilized metals were determined by inductively coupled plasma-atomic emission spectrometry (ICP-AES) and inductively coupled plasma-mass spectrometry (ICP-MS). CH3COOH pH 2.5 showed the greatest capacity to dissolve many elements. On the contrary, weakly acidic or alkaline environments did not favor the leachability of the elements. The best extraction capacity of the column with respect to the batch is statistically significant (p <0.05) for the elements Al, Fe, Ni and Zn, while the batch for P, Si, S. Pb, Cd, As were not detectable in cigarette butts, while Hg had an average concentration of 0.0502 μg/g. However, Hg was < LOD in all different leachants.
format article
author Carla Roselli
Ivan Fagiolino
Donatella Desideri
Davide Sisti
Maria Assunta Meli
author_facet Carla Roselli
Ivan Fagiolino
Donatella Desideri
Davide Sisti
Maria Assunta Meli
author_sort Carla Roselli
title Assessment of the release of metals from cigarette butts into the environment
title_short Assessment of the release of metals from cigarette butts into the environment
title_full Assessment of the release of metals from cigarette butts into the environment
title_fullStr Assessment of the release of metals from cigarette butts into the environment
title_full_unstemmed Assessment of the release of metals from cigarette butts into the environment
title_sort assessment of the release of metals from cigarette butts into the environment
publisher Public Library of Science (PLoS)
publishDate 2021
url https://doaj.org/article/c0e6f24179344f349c0017a1e75589f8
work_keys_str_mv AT carlaroselli assessmentofthereleaseofmetalsfromcigarettebuttsintotheenvironment
AT ivanfagiolino assessmentofthereleaseofmetalsfromcigarettebuttsintotheenvironment
AT donatelladesideri assessmentofthereleaseofmetalsfromcigarettebuttsintotheenvironment
AT davidesisti assessmentofthereleaseofmetalsfromcigarettebuttsintotheenvironment
AT mariaassuntameli assessmentofthereleaseofmetalsfromcigarettebuttsintotheenvironment
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