Efficient trapping of cesium ions in water by titanate nanosheets: experimental and theoretical studies

In recent years, TNS has attracted wide attention because of its simplicity in synthesis and high efficiency in ion exchange. The adsorption of cesium ions in aqueous solution by TNS was investigated in this study. Results show that the removal rate of Cs (I) is about 88% when pH = 5.00 ± 0.05, C0 =...

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Autores principales: Luyao Lin, Ye Li, Jie Wan, Cong Liu, Xiaoli Wang, Yixin Yin
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Lenguaje:EN
Publicado: IWA Publishing 2021
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spelling oai:doaj.org-article:c107c117b20b4642ada972cf703dc39f2021-11-05T21:16:42ZEfficient trapping of cesium ions in water by titanate nanosheets: experimental and theoretical studies1751-231X10.2166/wpt.2021.058https://doaj.org/article/c107c117b20b4642ada972cf703dc39f2021-10-01T00:00:00Zhttp://wpt.iwaponline.com/content/16/4/1128https://doaj.org/toc/1751-231XIn recent years, TNS has attracted wide attention because of its simplicity in synthesis and high efficiency in ion exchange. The adsorption of cesium ions in aqueous solution by TNS was investigated in this study. Results show that the removal rate of Cs (I) is about 88% when pH = 5.00 ± 0.05, C0 = 10 ppm and CTNS = 0.1 g/L. The adsorption equilibrium is reached in about 20 minutes and best fits the pseudo-second order model, R2 = 0.9998; compared with the Freundlich isotherm adsorption model and Temkin model, the Langmuir model has the best fitting effect, R2 = 0.9903. The fitting results show the maximum adsorption capacity of TNS for Cs (I) is 200.00 mg/g. The main adsorption mechanism of TNS to cesium ion is ion exchange. Therefore, TNS can be used as a potential adsorbent for effectively adsorbing Cs-containing wastewater. HIGHLIGHTS The removal of Cs (I) from aqueous solutions by TNS was firstly studied.; TNS showed a high adsorption capacity for Cs (I).; The solution pH played a significant role in the adsorption process of Cs (I).; TNS exhibited an excellent selectivity for Cs (I) in the interference of common cations.; The adsorption mechanism was the ion exchange between the interlayer Na (I) of TNS and Cs (I).;Luyao LinYe LiJie WanCong LiuXiaoli WangYixin YinIWA Publishingarticleadsorptioncesiummechanism of actiontitanate nanosheetEnvironmental technology. Sanitary engineeringTD1-1066ENWater Practice and Technology, Vol 16, Iss 4, Pp 1128-1140 (2021)
institution DOAJ
collection DOAJ
language EN
topic adsorption
cesium
mechanism of action
titanate nanosheet
Environmental technology. Sanitary engineering
TD1-1066
spellingShingle adsorption
cesium
mechanism of action
titanate nanosheet
Environmental technology. Sanitary engineering
TD1-1066
Luyao Lin
Ye Li
Jie Wan
Cong Liu
Xiaoli Wang
Yixin Yin
Efficient trapping of cesium ions in water by titanate nanosheets: experimental and theoretical studies
description In recent years, TNS has attracted wide attention because of its simplicity in synthesis and high efficiency in ion exchange. The adsorption of cesium ions in aqueous solution by TNS was investigated in this study. Results show that the removal rate of Cs (I) is about 88% when pH = 5.00 ± 0.05, C0 = 10 ppm and CTNS = 0.1 g/L. The adsorption equilibrium is reached in about 20 minutes and best fits the pseudo-second order model, R2 = 0.9998; compared with the Freundlich isotherm adsorption model and Temkin model, the Langmuir model has the best fitting effect, R2 = 0.9903. The fitting results show the maximum adsorption capacity of TNS for Cs (I) is 200.00 mg/g. The main adsorption mechanism of TNS to cesium ion is ion exchange. Therefore, TNS can be used as a potential adsorbent for effectively adsorbing Cs-containing wastewater. HIGHLIGHTS The removal of Cs (I) from aqueous solutions by TNS was firstly studied.; TNS showed a high adsorption capacity for Cs (I).; The solution pH played a significant role in the adsorption process of Cs (I).; TNS exhibited an excellent selectivity for Cs (I) in the interference of common cations.; The adsorption mechanism was the ion exchange between the interlayer Na (I) of TNS and Cs (I).;
format article
author Luyao Lin
Ye Li
Jie Wan
Cong Liu
Xiaoli Wang
Yixin Yin
author_facet Luyao Lin
Ye Li
Jie Wan
Cong Liu
Xiaoli Wang
Yixin Yin
author_sort Luyao Lin
title Efficient trapping of cesium ions in water by titanate nanosheets: experimental and theoretical studies
title_short Efficient trapping of cesium ions in water by titanate nanosheets: experimental and theoretical studies
title_full Efficient trapping of cesium ions in water by titanate nanosheets: experimental and theoretical studies
title_fullStr Efficient trapping of cesium ions in water by titanate nanosheets: experimental and theoretical studies
title_full_unstemmed Efficient trapping of cesium ions in water by titanate nanosheets: experimental and theoretical studies
title_sort efficient trapping of cesium ions in water by titanate nanosheets: experimental and theoretical studies
publisher IWA Publishing
publishDate 2021
url https://doaj.org/article/c107c117b20b4642ada972cf703dc39f
work_keys_str_mv AT luyaolin efficienttrappingofcesiumionsinwaterbytitanatenanosheetsexperimentalandtheoreticalstudies
AT yeli efficienttrappingofcesiumionsinwaterbytitanatenanosheetsexperimentalandtheoreticalstudies
AT jiewan efficienttrappingofcesiumionsinwaterbytitanatenanosheetsexperimentalandtheoreticalstudies
AT congliu efficienttrappingofcesiumionsinwaterbytitanatenanosheetsexperimentalandtheoreticalstudies
AT xiaoliwang efficienttrappingofcesiumionsinwaterbytitanatenanosheetsexperimentalandtheoreticalstudies
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