Experimental and Theoretical DFT Investigations in the [2,3]-Wittig-Type Rearrangement of Propargyl/Allyl-Oxy-Pyrazolones
Here we report the synthesis of interesting 3-alkyl-4-hydroxy-1-aryl-4-(propa-1,2-dienyl)1<i>H</i>-pyrazol-5(4<i>H</i>)-ones and 9-alkyl-7-aryl-1-oxa-7,8-diazaspiro[4.4]nona-3,8-dien-6-ones, starting from 1,2-diaza-1,3-dienes (DDs) and propargyl alcohol. The reaction proceeds...
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Autores principales: | Lucia De Crescentini, Gianfranco Favi, Giacomo Mari, Gianluca Ciancaleoni, Marcello Costamagna, Stefania Santeusanio, Fabio Mantellini |
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Formato: | article |
Lenguaje: | EN |
Publicado: |
MDPI AG
2021
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Materias: | |
Acceso en línea: | https://doaj.org/article/c11df27f83ad4d3399334d012181b3a2 |
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