NiVCe-Layered Double Hydroxide as Multifunctional Nanomaterials for Energy and Sensor Applications

Multifunctional nanomaterials have been attracting increasing attention as solutions to the existing challenges in energy systems and sensing technologies. In this regard, multifunctional NiVCe-layered double hydroxide (NiVCe-LDH) nanoparticles were synthesized by the modified sol-gel method. The an...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: Josué M. Gonçalves, Irlan S. Lima, Nathália F. B. Azeredo, Diego P. Rocha, Abner de Siervo, Lúcio Angnes
Formato: article
Lenguaje:EN
Publicado: Frontiers Media S.A. 2021
Materias:
T
Acceso en línea:https://doaj.org/article/c15f34ea6dca457e97f474c6e96459de
Etiquetas: Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
id oai:doaj.org-article:c15f34ea6dca457e97f474c6e96459de
record_format dspace
spelling oai:doaj.org-article:c15f34ea6dca457e97f474c6e96459de2021-12-01T10:56:22ZNiVCe-Layered Double Hydroxide as Multifunctional Nanomaterials for Energy and Sensor Applications2296-801610.3389/fmats.2021.781900https://doaj.org/article/c15f34ea6dca457e97f474c6e96459de2021-11-01T00:00:00Zhttps://www.frontiersin.org/articles/10.3389/fmats.2021.781900/fullhttps://doaj.org/toc/2296-8016Multifunctional nanomaterials have been attracting increasing attention as solutions to the existing challenges in energy systems and sensing technologies. In this regard, multifunctional NiVCe-layered double hydroxide (NiVCe-LDH) nanoparticles were synthesized by the modified sol-gel method. The analysis of this material demonstrated excellent potential for its utilization as electrode materials for hybrid supercapacitor, oxygen evolution reaction (OER), and sensor applications. The NiVCe-LDH nanoparticles delivered a specific charge of 740 C g−1 at 10 A g−1 and decent rate performance (charge retention of 68.7% at 100 A g−1), showing excellent prospects as electrode material for hybrid energy storage devices. In addition, NiVCe-LDH nanoparticles have also been successfully applied as a proof-of-concept for OER, as confirmed by their low Tafel slope of 47 mV dec−1. Finally, trimetallic NiVCe-LDH-based screen-printed electrodes were developed for the sensing of hydrogen peroxide directly in a real complex mouthwash sample, achieving a satisfactory recovery value of around 98% using a fast and simple batch injection analysis procedure. These results allow us to predict the great potential of this trimetallic hydroxide for building electrochemical sensors with good perspectives as electroactive material for OER processes and energy storage technologies.Josué M. GonçalvesIrlan S. LimaNathália F. B. AzeredoDiego P. RochaAbner de SiervoLúcio AngnesFrontiers Media S.A.articlelayered double hydroxides (LDH)multifunctionalelectrocatalystoxygen evolution reaction (OER)hybrid supercapacitorelectrochemical sensorTechnologyTENFrontiers in Materials, Vol 8 (2021)
institution DOAJ
collection DOAJ
language EN
topic layered double hydroxides (LDH)
multifunctional
electrocatalyst
oxygen evolution reaction (OER)
hybrid supercapacitor
electrochemical sensor
Technology
T
spellingShingle layered double hydroxides (LDH)
multifunctional
electrocatalyst
oxygen evolution reaction (OER)
hybrid supercapacitor
electrochemical sensor
Technology
T
Josué M. Gonçalves
Irlan S. Lima
Nathália F. B. Azeredo
Diego P. Rocha
Abner de Siervo
Lúcio Angnes
NiVCe-Layered Double Hydroxide as Multifunctional Nanomaterials for Energy and Sensor Applications
description Multifunctional nanomaterials have been attracting increasing attention as solutions to the existing challenges in energy systems and sensing technologies. In this regard, multifunctional NiVCe-layered double hydroxide (NiVCe-LDH) nanoparticles were synthesized by the modified sol-gel method. The analysis of this material demonstrated excellent potential for its utilization as electrode materials for hybrid supercapacitor, oxygen evolution reaction (OER), and sensor applications. The NiVCe-LDH nanoparticles delivered a specific charge of 740 C g−1 at 10 A g−1 and decent rate performance (charge retention of 68.7% at 100 A g−1), showing excellent prospects as electrode material for hybrid energy storage devices. In addition, NiVCe-LDH nanoparticles have also been successfully applied as a proof-of-concept for OER, as confirmed by their low Tafel slope of 47 mV dec−1. Finally, trimetallic NiVCe-LDH-based screen-printed electrodes were developed for the sensing of hydrogen peroxide directly in a real complex mouthwash sample, achieving a satisfactory recovery value of around 98% using a fast and simple batch injection analysis procedure. These results allow us to predict the great potential of this trimetallic hydroxide for building electrochemical sensors with good perspectives as electroactive material for OER processes and energy storage technologies.
format article
author Josué M. Gonçalves
Irlan S. Lima
Nathália F. B. Azeredo
Diego P. Rocha
Abner de Siervo
Lúcio Angnes
author_facet Josué M. Gonçalves
Irlan S. Lima
Nathália F. B. Azeredo
Diego P. Rocha
Abner de Siervo
Lúcio Angnes
author_sort Josué M. Gonçalves
title NiVCe-Layered Double Hydroxide as Multifunctional Nanomaterials for Energy and Sensor Applications
title_short NiVCe-Layered Double Hydroxide as Multifunctional Nanomaterials for Energy and Sensor Applications
title_full NiVCe-Layered Double Hydroxide as Multifunctional Nanomaterials for Energy and Sensor Applications
title_fullStr NiVCe-Layered Double Hydroxide as Multifunctional Nanomaterials for Energy and Sensor Applications
title_full_unstemmed NiVCe-Layered Double Hydroxide as Multifunctional Nanomaterials for Energy and Sensor Applications
title_sort nivce-layered double hydroxide as multifunctional nanomaterials for energy and sensor applications
publisher Frontiers Media S.A.
publishDate 2021
url https://doaj.org/article/c15f34ea6dca457e97f474c6e96459de
work_keys_str_mv AT josuemgoncalves nivcelayereddoublehydroxideasmultifunctionalnanomaterialsforenergyandsensorapplications
AT irlanslima nivcelayereddoublehydroxideasmultifunctionalnanomaterialsforenergyandsensorapplications
AT nathaliafbazeredo nivcelayereddoublehydroxideasmultifunctionalnanomaterialsforenergyandsensorapplications
AT diegoprocha nivcelayereddoublehydroxideasmultifunctionalnanomaterialsforenergyandsensorapplications
AT abnerdesiervo nivcelayereddoublehydroxideasmultifunctionalnanomaterialsforenergyandsensorapplications
AT lucioangnes nivcelayereddoublehydroxideasmultifunctionalnanomaterialsforenergyandsensorapplications
_version_ 1718405256592752640