Control of self-assembly pathways toward conglomerate and racemic supramolecular polymers

Homo- and heterochiral aggregation is a process of interest to prebiotic and chiral separation chemistry. Here, the authors analyze the self-assembly of a racemic mixture into 1D supramolecular polymers and find homochiral aggregation into conglomerates under kinetic control, while under thermodynam...

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Main Authors:	Marius Wehner, Merle Insa Silja Röhr, Vladimir Stepanenko, Frank Würthner
Format:	article
Language:	EN
Published:	Nature Portfolio 2020
Subjects:	Science Q
Online Access:	https://doaj.org/article/c1dc75a5d6784c59828f46fcd204348a
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id	oai:doaj.org-article:c1dc75a5d6784c59828f46fcd204348a
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spelling	oai:doaj.org-article:c1dc75a5d6784c59828f46fcd204348a2021-12-02T17:31:08ZControl of self-assembly pathways toward conglomerate and racemic supramolecular polymers10.1038/s41467-020-19189-82041-1723https://doaj.org/article/c1dc75a5d6784c59828f46fcd204348a2020-10-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-19189-8https://doaj.org/toc/2041-1723Homo- and heterochiral aggregation is a process of interest to prebiotic and chiral separation chemistry. Here, the authors analyze the self-assembly of a racemic mixture into 1D supramolecular polymers and find homochiral aggregation into conglomerates under kinetic control, while under thermodynamic control a racemic polymer is formed.Marius WehnerMerle Insa Silja RöhrVladimir StepanenkoFrank WürthnerNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-10 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Marius Wehner Merle Insa Silja Röhr Vladimir Stepanenko Frank Würthner Control of self-assembly pathways toward conglomerate and racemic supramolecular polymers
description	Homo- and heterochiral aggregation is a process of interest to prebiotic and chiral separation chemistry. Here, the authors analyze the self-assembly of a racemic mixture into 1D supramolecular polymers and find homochiral aggregation into conglomerates under kinetic control, while under thermodynamic control a racemic polymer is formed.
format	article
author	Marius Wehner Merle Insa Silja Röhr Vladimir Stepanenko Frank Würthner
author_facet	Marius Wehner Merle Insa Silja Röhr Vladimir Stepanenko Frank Würthner
author_sort	Marius Wehner
title	Control of self-assembly pathways toward conglomerate and racemic supramolecular polymers
title_short	Control of self-assembly pathways toward conglomerate and racemic supramolecular polymers
title_full	Control of self-assembly pathways toward conglomerate and racemic supramolecular polymers
title_fullStr	Control of self-assembly pathways toward conglomerate and racemic supramolecular polymers
title_full_unstemmed	Control of self-assembly pathways toward conglomerate and racemic supramolecular polymers
title_sort	control of self-assembly pathways toward conglomerate and racemic supramolecular polymers
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/c1dc75a5d6784c59828f46fcd204348a
work_keys_str_mv	AT mariuswehner controlofselfassemblypathwaystowardconglomerateandracemicsupramolecularpolymers AT merleinsasiljarohr controlofselfassemblypathwaystowardconglomerateandracemicsupramolecularpolymers AT vladimirstepanenko controlofselfassemblypathwaystowardconglomerateandracemicsupramolecularpolymers AT frankwurthner controlofselfassemblypathwaystowardconglomerateandracemicsupramolecularpolymers
_version_	1718380698130186240

Control of self-assembly pathways toward conglomerate and racemic supramolecular polymers

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