Synthesis and crystal structure of two Co(III) α-dioximates with the formula [Co(DH)2(PPh3)(H2O)]2[EF6]·nH2O

The [Co(DH)2(PPh3)(H2O)]2[TiF6]·2.5H2O (1) and Co(DH)2(PPh3)(H2O)]2[ZrF6]·3.75H2O (2) complexes have been obtained from the CoEF6·6H2O - 2DH2 - PPh3 system, where DH2 is the dimethylglyoxime, E is Ti or Zr, and PPh3 is triphenylphosphine. The structure and composition of these complexes have bee...

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Auteurs principaux: Rija, Andrei, Bouroş, Pavlina, Coropceanu, Eduard, Bologa, Olga, Gdaniec, Maria, Vologzhanina, A., Bulhac, Ion
Format: article
Langue:EN
Publié: D.Ghitu Institute of Electronic Engineering and Nanotechnologies 2010
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Accès en ligne:https://doaj.org/article/c210947a62194e1e92b72ff7ac8a07d2
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