Photocatalytic three-component asymmetric sulfonylation via direct C(sp3)-H functionalization

The direct and selective C(sp3)-H functionalization of cycloalkanes and alkanes is useful in organic synthesis but its application to asymmetric catalysis has been less explored. Here, the authors demonstrate the incorporation of a dual asymmetric photocatalyst which leads to the development of asym...

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Autores principales: Shi Cao, Wei Hong, Ziqi Ye, Lei Gong
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/c2256429a5be49b0a2ab5f1593ffd207
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spelling oai:doaj.org-article:c2256429a5be49b0a2ab5f1593ffd2072021-12-02T17:33:40ZPhotocatalytic three-component asymmetric sulfonylation via direct C(sp3)-H functionalization10.1038/s41467-021-22690-32041-1723https://doaj.org/article/c2256429a5be49b0a2ab5f1593ffd2072021-04-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-22690-3https://doaj.org/toc/2041-1723The direct and selective C(sp3)-H functionalization of cycloalkanes and alkanes is useful in organic synthesis but its application to asymmetric catalysis has been less explored. Here, the authors demonstrate the incorporation of a dual asymmetric photocatalyst which leads to the development of asymmetric sulfonylation involving direct functionalization of cycloalkanes, alkanes, toluene derivatives or ethers.Shi CaoWei HongZiqi YeLei GongNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-12 (2021)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Shi Cao
Wei Hong
Ziqi Ye
Lei Gong
Photocatalytic three-component asymmetric sulfonylation via direct C(sp3)-H functionalization
description The direct and selective C(sp3)-H functionalization of cycloalkanes and alkanes is useful in organic synthesis but its application to asymmetric catalysis has been less explored. Here, the authors demonstrate the incorporation of a dual asymmetric photocatalyst which leads to the development of asymmetric sulfonylation involving direct functionalization of cycloalkanes, alkanes, toluene derivatives or ethers.
format article
author Shi Cao
Wei Hong
Ziqi Ye
Lei Gong
author_facet Shi Cao
Wei Hong
Ziqi Ye
Lei Gong
author_sort Shi Cao
title Photocatalytic three-component asymmetric sulfonylation via direct C(sp3)-H functionalization
title_short Photocatalytic three-component asymmetric sulfonylation via direct C(sp3)-H functionalization
title_full Photocatalytic three-component asymmetric sulfonylation via direct C(sp3)-H functionalization
title_fullStr Photocatalytic three-component asymmetric sulfonylation via direct C(sp3)-H functionalization
title_full_unstemmed Photocatalytic three-component asymmetric sulfonylation via direct C(sp3)-H functionalization
title_sort photocatalytic three-component asymmetric sulfonylation via direct c(sp3)-h functionalization
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/c2256429a5be49b0a2ab5f1593ffd207
work_keys_str_mv AT shicao photocatalyticthreecomponentasymmetricsulfonylationviadirectcsp3hfunctionalization
AT weihong photocatalyticthreecomponentasymmetricsulfonylationviadirectcsp3hfunctionalization
AT ziqiye photocatalyticthreecomponentasymmetricsulfonylationviadirectcsp3hfunctionalization
AT leigong photocatalyticthreecomponentasymmetricsulfonylationviadirectcsp3hfunctionalization
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