Photocatalytic three-component asymmetric sulfonylation via direct C(sp3)-H functionalization
The direct and selective C(sp3)-H functionalization of cycloalkanes and alkanes is useful in organic synthesis but its application to asymmetric catalysis has been less explored. Here, the authors demonstrate the incorporation of a dual asymmetric photocatalyst which leads to the development of asym...
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2021
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oai:doaj.org-article:c2256429a5be49b0a2ab5f1593ffd2072021-12-02T17:33:40ZPhotocatalytic three-component asymmetric sulfonylation via direct C(sp3)-H functionalization10.1038/s41467-021-22690-32041-1723https://doaj.org/article/c2256429a5be49b0a2ab5f1593ffd2072021-04-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-22690-3https://doaj.org/toc/2041-1723The direct and selective C(sp3)-H functionalization of cycloalkanes and alkanes is useful in organic synthesis but its application to asymmetric catalysis has been less explored. Here, the authors demonstrate the incorporation of a dual asymmetric photocatalyst which leads to the development of asymmetric sulfonylation involving direct functionalization of cycloalkanes, alkanes, toluene derivatives or ethers.Shi CaoWei HongZiqi YeLei GongNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-12 (2021) |
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Science Q Shi Cao Wei Hong Ziqi Ye Lei Gong Photocatalytic three-component asymmetric sulfonylation via direct C(sp3)-H functionalization |
description |
The direct and selective C(sp3)-H functionalization of cycloalkanes and alkanes is useful in organic synthesis but its application to asymmetric catalysis has been less explored. Here, the authors demonstrate the incorporation of a dual asymmetric photocatalyst which leads to the development of asymmetric sulfonylation involving direct functionalization of cycloalkanes, alkanes, toluene derivatives or ethers. |
format |
article |
author |
Shi Cao Wei Hong Ziqi Ye Lei Gong |
author_facet |
Shi Cao Wei Hong Ziqi Ye Lei Gong |
author_sort |
Shi Cao |
title |
Photocatalytic three-component asymmetric sulfonylation via direct C(sp3)-H functionalization |
title_short |
Photocatalytic three-component asymmetric sulfonylation via direct C(sp3)-H functionalization |
title_full |
Photocatalytic three-component asymmetric sulfonylation via direct C(sp3)-H functionalization |
title_fullStr |
Photocatalytic three-component asymmetric sulfonylation via direct C(sp3)-H functionalization |
title_full_unstemmed |
Photocatalytic three-component asymmetric sulfonylation via direct C(sp3)-H functionalization |
title_sort |
photocatalytic three-component asymmetric sulfonylation via direct c(sp3)-h functionalization |
publisher |
Nature Portfolio |
publishDate |
2021 |
url |
https://doaj.org/article/c2256429a5be49b0a2ab5f1593ffd207 |
work_keys_str_mv |
AT shicao photocatalyticthreecomponentasymmetricsulfonylationviadirectcsp3hfunctionalization AT weihong photocatalyticthreecomponentasymmetricsulfonylationviadirectcsp3hfunctionalization AT ziqiye photocatalyticthreecomponentasymmetricsulfonylationviadirectcsp3hfunctionalization AT leigong photocatalyticthreecomponentasymmetricsulfonylationviadirectcsp3hfunctionalization |
_version_ |
1718379963577532416 |