A Keplerian Ag90 nest of Platonic and Archimedean polyhedra in different symmetry groups

Nested polyhedra are compelling but incredibly complex synthetic targets in cluster chemistry. Here, the authors synthesize a Ag90 nanocluster comprising three concentric polyhedra with apparently incompatible octahedral (Oh) and icosahedral (Ih) symmetry, a mathematical oddity that is solved by the...

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Autores principales: Yan-Min Su, Zhi Wang, Stan Schein, Chen-Ho Tung, Di Sun
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/c2a34738068148a48d07005ad39f76be
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Sumario:Nested polyhedra are compelling but incredibly complex synthetic targets in cluster chemistry. Here, the authors synthesize a Ag90 nanocluster comprising three concentric polyhedra with apparently incompatible octahedral (Oh) and icosahedral (Ih) symmetry, a mathematical oddity that is solved by the shells’ symmetric arrangement around rotational 2- and 3-fold axes.