Temperature-controlled repeatable scrambling and induced-sorting of building blocks between cubic assemblies

In this paper, the authors study the temperature-controlled dynamic behavior of a system of nanocubes self-assembled from two different building blocks. Non-intuitively, the disordered, equilibrium state (a mixture of heteroleptic cubes) and the ordered, out-of-equilibrium state (a mixture of homole...

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Autores principales: Yi-Yang Zhan, Tatsuo Kojima, Kentaro Ishii, Satoshi Takahashi, Yohei Haketa, Hiromitsu Maeda, Susumu Uchiyama, Shuichi Hiraoka
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/c3b2c176af4841adbe2b5fc1b9225dc9
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Sumario:In this paper, the authors study the temperature-controlled dynamic behavior of a system of nanocubes self-assembled from two different building blocks. Non-intuitively, the disordered, equilibrium state (a mixture of heteroleptic cubes) and the ordered, out-of-equilibrium state (a mixture of homoleptic cubes) are cycled by heating and subsequent rapid cooling.