Co-Precipitated Ni-Mg-Al Hydrotalcite-Derived Catalyst Promoted with Vanadium for CO<sub>2</sub> Methanation
Co-precipitated Ni-Mg-Al hydrotalcite-derived catalyst promoted with vanadium were synthesized with different V loadings (0–4 wt%) and studied in CO<sub>2</sub> methanation. The promotion with V significantly changes textural properties (specific surface area and mesoporosity) and improv...
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2021
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oai:doaj.org-article:c41a267a37544a4f948e86abed9a69252021-11-11T18:30:15ZCo-Precipitated Ni-Mg-Al Hydrotalcite-Derived Catalyst Promoted with Vanadium for CO<sub>2</sub> Methanation10.3390/molecules262165061420-3049https://doaj.org/article/c41a267a37544a4f948e86abed9a69252021-10-01T00:00:00Zhttps://www.mdpi.com/1420-3049/26/21/6506https://doaj.org/toc/1420-3049Co-precipitated Ni-Mg-Al hydrotalcite-derived catalyst promoted with vanadium were synthesized with different V loadings (0–4 wt%) and studied in CO<sub>2</sub> methanation. The promotion with V significantly changes textural properties (specific surface area and mesoporosity) and improves the dispersion of nickel. Moreover, the vanadium promotion strongly influences the surface basicity by increasing the total number of basic sites. An optimal loading of 2 wt% leads to the highest activity in CO<sub>2</sub> methanation, which is directly correlated with specific surface area, as well as the basic properties of the studied catalysts.Paulina SummaKatarzyna ŚwirkDominik WierzbickiMonika MotakIvo AlxneitMagnus RønningPatrick Da CostaMDPI AGarticlemethanationhydrotalcitevanadiumnickel catalystmixed oxidesCO<sub>2</sub> hydrogenationOrganic chemistryQD241-441ENMolecules, Vol 26, Iss 6506, p 6506 (2021) |
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DOAJ |
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topic |
methanation hydrotalcite vanadium nickel catalyst mixed oxides CO<sub>2</sub> hydrogenation Organic chemistry QD241-441 |
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methanation hydrotalcite vanadium nickel catalyst mixed oxides CO<sub>2</sub> hydrogenation Organic chemistry QD241-441 Paulina Summa Katarzyna Świrk Dominik Wierzbicki Monika Motak Ivo Alxneit Magnus Rønning Patrick Da Costa Co-Precipitated Ni-Mg-Al Hydrotalcite-Derived Catalyst Promoted with Vanadium for CO<sub>2</sub> Methanation |
description |
Co-precipitated Ni-Mg-Al hydrotalcite-derived catalyst promoted with vanadium were synthesized with different V loadings (0–4 wt%) and studied in CO<sub>2</sub> methanation. The promotion with V significantly changes textural properties (specific surface area and mesoporosity) and improves the dispersion of nickel. Moreover, the vanadium promotion strongly influences the surface basicity by increasing the total number of basic sites. An optimal loading of 2 wt% leads to the highest activity in CO<sub>2</sub> methanation, which is directly correlated with specific surface area, as well as the basic properties of the studied catalysts. |
format |
article |
author |
Paulina Summa Katarzyna Świrk Dominik Wierzbicki Monika Motak Ivo Alxneit Magnus Rønning Patrick Da Costa |
author_facet |
Paulina Summa Katarzyna Świrk Dominik Wierzbicki Monika Motak Ivo Alxneit Magnus Rønning Patrick Da Costa |
author_sort |
Paulina Summa |
title |
Co-Precipitated Ni-Mg-Al Hydrotalcite-Derived Catalyst Promoted with Vanadium for CO<sub>2</sub> Methanation |
title_short |
Co-Precipitated Ni-Mg-Al Hydrotalcite-Derived Catalyst Promoted with Vanadium for CO<sub>2</sub> Methanation |
title_full |
Co-Precipitated Ni-Mg-Al Hydrotalcite-Derived Catalyst Promoted with Vanadium for CO<sub>2</sub> Methanation |
title_fullStr |
Co-Precipitated Ni-Mg-Al Hydrotalcite-Derived Catalyst Promoted with Vanadium for CO<sub>2</sub> Methanation |
title_full_unstemmed |
Co-Precipitated Ni-Mg-Al Hydrotalcite-Derived Catalyst Promoted with Vanadium for CO<sub>2</sub> Methanation |
title_sort |
co-precipitated ni-mg-al hydrotalcite-derived catalyst promoted with vanadium for co<sub>2</sub> methanation |
publisher |
MDPI AG |
publishDate |
2021 |
url |
https://doaj.org/article/c41a267a37544a4f948e86abed9a6925 |
work_keys_str_mv |
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