Facile Synthesis of Carbon Nanospheres with High Capability to Inhale Selenium Powder for Electrochemical Energy Storage

Carbon–selenium composite positive electrode (CSs@Se) is engineered in this project using a melt diffusion approach with glucose as a precursor, and it demonstrates good electrochemical performance for lithium–selenium batteries. X-ray diffraction (XRD) and scanning electron microscopy (SEM) with ED...

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Autores principales: Mustafa Khan, Xuli Ding, Hongda Zhao, Xinrong Ma, Yuxin Wang
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Publicado: MDPI AG 2021
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spelling oai:doaj.org-article:c42636d129cb40188abfa1885e28a7e32021-11-25T18:13:20ZFacile Synthesis of Carbon Nanospheres with High Capability to Inhale Selenium Powder for Electrochemical Energy Storage10.3390/ma142267601996-1944https://doaj.org/article/c42636d129cb40188abfa1885e28a7e32021-11-01T00:00:00Zhttps://www.mdpi.com/1996-1944/14/22/6760https://doaj.org/toc/1996-1944Carbon–selenium composite positive electrode (CSs@Se) is engineered in this project using a melt diffusion approach with glucose as a precursor, and it demonstrates good electrochemical performance for lithium–selenium batteries. X-ray diffraction (XRD) and scanning electron microscopy (SEM) with EDS analysis are used to characterize the newly designed CSs@Se electrode. To complete the evaluation, electrochemical characterization such as charge–discharge (rate performance and cycle stability), cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS) tests are done. The findings show that selenium particles are distributed uniformly in mono-sized carbon spheres with enormous surface areas. Furthermore, the charge–discharge test demonstrates that the CSs@Se cathode has a rate performance of 104 mA h g<sup>−1</sup> even at current density of 2500 mA g<sup>−1</sup> and can sustain stable cycling for 70 cycles with a specific capacity of 270 mA h g<sup>−1</sup> at current density of 25 mA g<sup>−1</sup>. The homogeneous diffusion of selenium particles in the produced spheres is credited with an improved electrochemical performance.Mustafa KhanXuli DingHongda ZhaoXinrong MaYuxin WangMDPI AGarticlecarbon nanospheresseleniumLi–Se batteryTechnologyTElectrical engineering. Electronics. Nuclear engineeringTK1-9971Engineering (General). Civil engineering (General)TA1-2040MicroscopyQH201-278.5Descriptive and experimental mechanicsQC120-168.85ENMaterials, Vol 14, Iss 6760, p 6760 (2021)
institution DOAJ
collection DOAJ
language EN
topic carbon nanospheres
selenium
Li–Se battery
Technology
T
Electrical engineering. Electronics. Nuclear engineering
TK1-9971
Engineering (General). Civil engineering (General)
TA1-2040
Microscopy
QH201-278.5
Descriptive and experimental mechanics
QC120-168.85
spellingShingle carbon nanospheres
selenium
Li–Se battery
Technology
T
Electrical engineering. Electronics. Nuclear engineering
TK1-9971
Engineering (General). Civil engineering (General)
TA1-2040
Microscopy
QH201-278.5
Descriptive and experimental mechanics
QC120-168.85
Mustafa Khan
Xuli Ding
Hongda Zhao
Xinrong Ma
Yuxin Wang
Facile Synthesis of Carbon Nanospheres with High Capability to Inhale Selenium Powder for Electrochemical Energy Storage
description Carbon–selenium composite positive electrode (CSs@Se) is engineered in this project using a melt diffusion approach with glucose as a precursor, and it demonstrates good electrochemical performance for lithium–selenium batteries. X-ray diffraction (XRD) and scanning electron microscopy (SEM) with EDS analysis are used to characterize the newly designed CSs@Se electrode. To complete the evaluation, electrochemical characterization such as charge–discharge (rate performance and cycle stability), cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS) tests are done. The findings show that selenium particles are distributed uniformly in mono-sized carbon spheres with enormous surface areas. Furthermore, the charge–discharge test demonstrates that the CSs@Se cathode has a rate performance of 104 mA h g<sup>−1</sup> even at current density of 2500 mA g<sup>−1</sup> and can sustain stable cycling for 70 cycles with a specific capacity of 270 mA h g<sup>−1</sup> at current density of 25 mA g<sup>−1</sup>. The homogeneous diffusion of selenium particles in the produced spheres is credited with an improved electrochemical performance.
format article
author Mustafa Khan
Xuli Ding
Hongda Zhao
Xinrong Ma
Yuxin Wang
author_facet Mustafa Khan
Xuli Ding
Hongda Zhao
Xinrong Ma
Yuxin Wang
author_sort Mustafa Khan
title Facile Synthesis of Carbon Nanospheres with High Capability to Inhale Selenium Powder for Electrochemical Energy Storage
title_short Facile Synthesis of Carbon Nanospheres with High Capability to Inhale Selenium Powder for Electrochemical Energy Storage
title_full Facile Synthesis of Carbon Nanospheres with High Capability to Inhale Selenium Powder for Electrochemical Energy Storage
title_fullStr Facile Synthesis of Carbon Nanospheres with High Capability to Inhale Selenium Powder for Electrochemical Energy Storage
title_full_unstemmed Facile Synthesis of Carbon Nanospheres with High Capability to Inhale Selenium Powder for Electrochemical Energy Storage
title_sort facile synthesis of carbon nanospheres with high capability to inhale selenium powder for electrochemical energy storage
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/c42636d129cb40188abfa1885e28a7e3
work_keys_str_mv AT mustafakhan facilesynthesisofcarbonnanosphereswithhighcapabilitytoinhaleseleniumpowderforelectrochemicalenergystorage
AT xuliding facilesynthesisofcarbonnanosphereswithhighcapabilitytoinhaleseleniumpowderforelectrochemicalenergystorage
AT hongdazhao facilesynthesisofcarbonnanosphereswithhighcapabilitytoinhaleseleniumpowderforelectrochemicalenergystorage
AT xinrongma facilesynthesisofcarbonnanosphereswithhighcapabilitytoinhaleseleniumpowderforelectrochemicalenergystorage
AT yuxinwang facilesynthesisofcarbonnanosphereswithhighcapabilitytoinhaleseleniumpowderforelectrochemicalenergystorage
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