Differentiation between enamines and tautomerizable imines in the oxidation reaction with TEMPO

Tautomerization of imines into enamines is the basis of their similar reactivity; however, minor structural changes may lead to different outcomes. Here, the authors show that the reaction of cyclohexanone and amines in presence of TEMPO affords either α-amino-enones or arylamines depending on the i...

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Autores principales:	Xiaoming Jie, Yaping Shang, Zhe-Ning Chen, Xiaofeng Zhang, Wei Zhuang, Weiping Su
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/c44bba21b32847a1bb2875d952ada440
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spelling	oai:doaj.org-article:c44bba21b32847a1bb2875d952ada4402021-12-02T16:56:57ZDifferentiation between enamines and tautomerizable imines in the oxidation reaction with TEMPO10.1038/s41467-018-07534-x2041-1723https://doaj.org/article/c44bba21b32847a1bb2875d952ada4402018-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-07534-xhttps://doaj.org/toc/2041-1723Tautomerization of imines into enamines is the basis of their similar reactivity; however, minor structural changes may lead to different outcomes. Here, the authors show that the reaction of cyclohexanone and amines in presence of TEMPO affords either α-amino-enones or arylamines depending on the intermediate imine structure.Xiaoming JieYaping ShangZhe-Ning ChenXiaofeng ZhangWei ZhuangWeiping SuNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-10 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Xiaoming Jie Yaping Shang Zhe-Ning Chen Xiaofeng Zhang Wei Zhuang Weiping Su Differentiation between enamines and tautomerizable imines in the oxidation reaction with TEMPO
description	Tautomerization of imines into enamines is the basis of their similar reactivity; however, minor structural changes may lead to different outcomes. Here, the authors show that the reaction of cyclohexanone and amines in presence of TEMPO affords either α-amino-enones or arylamines depending on the intermediate imine structure.
format	article
author	Xiaoming Jie Yaping Shang Zhe-Ning Chen Xiaofeng Zhang Wei Zhuang Weiping Su
author_facet	Xiaoming Jie Yaping Shang Zhe-Ning Chen Xiaofeng Zhang Wei Zhuang Weiping Su
author_sort	Xiaoming Jie
title	Differentiation between enamines and tautomerizable imines in the oxidation reaction with TEMPO
title_short	Differentiation between enamines and tautomerizable imines in the oxidation reaction with TEMPO
title_full	Differentiation between enamines and tautomerizable imines in the oxidation reaction with TEMPO
title_fullStr	Differentiation between enamines and tautomerizable imines in the oxidation reaction with TEMPO
title_full_unstemmed	Differentiation between enamines and tautomerizable imines in the oxidation reaction with TEMPO
title_sort	differentiation between enamines and tautomerizable imines in the oxidation reaction with tempo
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/c44bba21b32847a1bb2875d952ada440
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Differentiation between enamines and tautomerizable imines in the oxidation reaction with TEMPO

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