Empowering alcohols as carbonyl surrogates for Grignard-type reactions

Alcohols are more naturally abundant than carbonyl compounds, which in turn are well known for their reactivity in Grignard reactions. Here, the authors showcase a distinct Grignard-like reactivity by using alcohols as coupling partners with hydrazones and synthesize more complex alcohols under ruth...

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Autores principales:	Chen-Chen Li, Haining Wang, Malcolm M. Sim, Zihang Qiu, Zhang-Pei Chen, Rustam Z. Khaliullin, Chao-Jun Li
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/c45718de9c8b46ddba7d11418ba37090
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spelling	oai:doaj.org-article:c45718de9c8b46ddba7d11418ba370902021-12-02T15:37:13ZEmpowering alcohols as carbonyl surrogates for Grignard-type reactions10.1038/s41467-020-19857-92041-1723https://doaj.org/article/c45718de9c8b46ddba7d11418ba370902020-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-19857-9https://doaj.org/toc/2041-1723Alcohols are more naturally abundant than carbonyl compounds, which in turn are well known for their reactivity in Grignard reactions. Here, the authors showcase a distinct Grignard-like reactivity by using alcohols as coupling partners with hydrazones and synthesize more complex alcohols under ruthenium catalysis.Chen-Chen LiHaining WangMalcolm M. SimZihang QiuZhang-Pei ChenRustam Z. KhaliullinChao-Jun LiNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-9 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Chen-Chen Li Haining Wang Malcolm M. Sim Zihang Qiu Zhang-Pei Chen Rustam Z. Khaliullin Chao-Jun Li Empowering alcohols as carbonyl surrogates for Grignard-type reactions
description	Alcohols are more naturally abundant than carbonyl compounds, which in turn are well known for their reactivity in Grignard reactions. Here, the authors showcase a distinct Grignard-like reactivity by using alcohols as coupling partners with hydrazones and synthesize more complex alcohols under ruthenium catalysis.
format	article
author	Chen-Chen Li Haining Wang Malcolm M. Sim Zihang Qiu Zhang-Pei Chen Rustam Z. Khaliullin Chao-Jun Li
author_facet	Chen-Chen Li Haining Wang Malcolm M. Sim Zihang Qiu Zhang-Pei Chen Rustam Z. Khaliullin Chao-Jun Li
author_sort	Chen-Chen Li
title	Empowering alcohols as carbonyl surrogates for Grignard-type reactions
title_short	Empowering alcohols as carbonyl surrogates for Grignard-type reactions
title_full	Empowering alcohols as carbonyl surrogates for Grignard-type reactions
title_fullStr	Empowering alcohols as carbonyl surrogates for Grignard-type reactions
title_full_unstemmed	Empowering alcohols as carbonyl surrogates for Grignard-type reactions
title_sort	empowering alcohols as carbonyl surrogates for grignard-type reactions
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/c45718de9c8b46ddba7d11418ba37090
work_keys_str_mv	AT chenchenli empoweringalcoholsascarbonylsurrogatesforgrignardtypereactions AT hainingwang empoweringalcoholsascarbonylsurrogatesforgrignardtypereactions AT malcolmmsim empoweringalcoholsascarbonylsurrogatesforgrignardtypereactions AT zihangqiu empoweringalcoholsascarbonylsurrogatesforgrignardtypereactions AT zhangpeichen empoweringalcoholsascarbonylsurrogatesforgrignardtypereactions AT rustamzkhaliullin empoweringalcoholsascarbonylsurrogatesforgrignardtypereactions AT chaojunli empoweringalcoholsascarbonylsurrogatesforgrignardtypereactions
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Empowering alcohols as carbonyl surrogates for Grignard-type reactions

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