Control of crystallization behaviour of supercooled liquid composed of lithium disilicate on platinum substrate

Abstract Crystalline lithium disilicate (Li2Si2O5, LS2) materials, which have excellent mechanical properties with high transparency, should be obtained efficiently through the crystallization of supercooled liquid composed of LS2. However, in addition to LS2, a lithium monosilicate (Li2SiO3, LS) ph...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Masanori Tashiro, Sohei Sukenaga, Hiroyuki Shibata
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2017
Materias:	Medicine R Science Q
Acceso en línea:	https://doaj.org/article/c4bc73564cc944bfa6bf6c65e5661e1a
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:c4bc73564cc944bfa6bf6c65e5661e1a
record_format	dspace
spelling	oai:doaj.org-article:c4bc73564cc944bfa6bf6c65e5661e1a2021-12-02T11:52:34ZControl of crystallization behaviour of supercooled liquid composed of lithium disilicate on platinum substrate10.1038/s41598-017-06306-92045-2322https://doaj.org/article/c4bc73564cc944bfa6bf6c65e5661e1a2017-07-01T00:00:00Zhttps://doi.org/10.1038/s41598-017-06306-9https://doaj.org/toc/2045-2322Abstract Crystalline lithium disilicate (Li2Si2O5, LS2) materials, which have excellent mechanical properties with high transparency, should be obtained efficiently through the crystallization of supercooled liquid composed of LS2. However, in addition to LS2, a lithium monosilicate (Li2SiO3, LS) phase is also precipitated during the crystallization of the liquid. The precipitation of the LS phase renders it difficult to obtain a single-phase LS2 material. Here, we show that by altering the oxygen partial pressure, it is possible to change the selectivity of the precipitated phase by controlling the interfacial phenomena that occur between the liquid and platinum contact material. During cooling of the supercooled liquid, the type of precipitated phase can be controlled by optimizing the atmosphere and type of contact material. This methodology can be applied for the fabrication of other functional materials and does not require the use of other additives.Masanori TashiroSohei SukenagaHiroyuki ShibataNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 7, Iss 1, Pp 1-6 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Medicine R Science Q
spellingShingle	Medicine R Science Q Masanori Tashiro Sohei Sukenaga Hiroyuki Shibata Control of crystallization behaviour of supercooled liquid composed of lithium disilicate on platinum substrate
description	Abstract Crystalline lithium disilicate (Li2Si2O5, LS2) materials, which have excellent mechanical properties with high transparency, should be obtained efficiently through the crystallization of supercooled liquid composed of LS2. However, in addition to LS2, a lithium monosilicate (Li2SiO3, LS) phase is also precipitated during the crystallization of the liquid. The precipitation of the LS phase renders it difficult to obtain a single-phase LS2 material. Here, we show that by altering the oxygen partial pressure, it is possible to change the selectivity of the precipitated phase by controlling the interfacial phenomena that occur between the liquid and platinum contact material. During cooling of the supercooled liquid, the type of precipitated phase can be controlled by optimizing the atmosphere and type of contact material. This methodology can be applied for the fabrication of other functional materials and does not require the use of other additives.
format	article
author	Masanori Tashiro Sohei Sukenaga Hiroyuki Shibata
author_facet	Masanori Tashiro Sohei Sukenaga Hiroyuki Shibata
author_sort	Masanori Tashiro
title	Control of crystallization behaviour of supercooled liquid composed of lithium disilicate on platinum substrate
title_short	Control of crystallization behaviour of supercooled liquid composed of lithium disilicate on platinum substrate
title_full	Control of crystallization behaviour of supercooled liquid composed of lithium disilicate on platinum substrate
title_fullStr	Control of crystallization behaviour of supercooled liquid composed of lithium disilicate on platinum substrate
title_full_unstemmed	Control of crystallization behaviour of supercooled liquid composed of lithium disilicate on platinum substrate
title_sort	control of crystallization behaviour of supercooled liquid composed of lithium disilicate on platinum substrate
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/c4bc73564cc944bfa6bf6c65e5661e1a
work_keys_str_mv	AT masanoritashiro controlofcrystallizationbehaviourofsupercooledliquidcomposedoflithiumdisilicateonplatinumsubstrate AT soheisukenaga controlofcrystallizationbehaviourofsupercooledliquidcomposedoflithiumdisilicateonplatinumsubstrate AT hiroyukishibata controlofcrystallizationbehaviourofsupercooledliquidcomposedoflithiumdisilicateonplatinumsubstrate
_version_	1718395009177223168

Control of crystallization behaviour of supercooled liquid composed of lithium disilicate on platinum substrate

Ejemplares similares