Bispyrenylalkane Chemosensor for the Naked-eye Detection of Nitro-explosives
Pyrene-based compounds have a great potential as fluorescent chemosensors for various analytes including common nitro-explosives, such as 2,4,6-trinitrotoluene (TNT). Compounds having two pyrene units in one molecule, such as bispyrenylalkanes, are able to form stable, bright emissive in a visual wa...
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| Autores principales: | , , , , , , , , |
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| Formato: | article |
| Lenguaje: | EN RU |
| Publicado: |
Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina
2021
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| Materias: | |
| Acceso en línea: | https://doaj.org/article/c4f280ded698460b9aa821ad53316855 |
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| Sumario: | Pyrene-based compounds have a great potential as fluorescent chemosensors for various analytes including common nitro-explosives, such as 2,4,6-trinitrotoluene (TNT). Compounds having two pyrene units in one molecule, such as bispyrenylalkanes, are able to form stable, bright emissive in a visual wavelength region excimers both in non-polar and polar environments. In this work we wish to report that in non-polar solvents the excimer has poor chemosensing properties while in aqueous solutions it provides significant “turn-off” fluorescence response to TNT in the sub-nanomolar concentrations. |
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