syn-Selective alkylarylation of terminal alkynes via the combination of photoredox and nickel catalysis
Converting alkynes into alkenes with high stereoselectivity via two consecutive C-C bond forming steps is a desirable process, yet very challenging. Here, the authors describe a dual photoredox-nickel catalytic system for the regio- and syn-selective alkylarylation of terminal alkynes with alkyl oxa...
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Autores principales: | , , , , |
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Formato: | article |
Lenguaje: | EN |
Publicado: |
Nature Portfolio
2018
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Materias: | |
Acceso en línea: | https://doaj.org/article/c4f51708a4e34e558cb4dc711bb94cf0 |
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Sumario: | Converting alkynes into alkenes with high stereoselectivity via two consecutive C-C bond forming steps is a desirable process, yet very challenging. Here, the authors describe a dual photoredox-nickel catalytic system for the regio- and syn-selective alkylarylation of terminal alkynes with alkyl oxalates and aryl bromides. |
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