syn-Selective alkylarylation of terminal alkynes via the combination of photoredox and nickel catalysis

Converting alkynes into alkenes with high stereoselectivity via two consecutive C-C bond forming steps is a desirable process, yet very challenging. Here, the authors describe a dual photoredox-nickel catalytic system for the regio- and syn-selective alkylarylation of terminal alkynes with alkyl oxa...

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Autores principales:	Lei Guo, Fan Song, Shengqing Zhu, Huan Li, Lingling Chu
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/c4f51708a4e34e558cb4dc711bb94cf0
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spelling	oai:doaj.org-article:c4f51708a4e34e558cb4dc711bb94cf02021-12-02T14:39:46Zsyn-Selective alkylarylation of terminal alkynes via the combination of photoredox and nickel catalysis10.1038/s41467-018-06904-92041-1723https://doaj.org/article/c4f51708a4e34e558cb4dc711bb94cf02018-10-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-06904-9https://doaj.org/toc/2041-1723Converting alkynes into alkenes with high stereoselectivity via two consecutive C-C bond forming steps is a desirable process, yet very challenging. Here, the authors describe a dual photoredox-nickel catalytic system for the regio- and syn-selective alkylarylation of terminal alkynes with alkyl oxalates and aryl bromides.Lei GuoFan SongShengqing ZhuHuan LiLingling ChuNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-8 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Lei Guo Fan Song Shengqing Zhu Huan Li Lingling Chu syn-Selective alkylarylation of terminal alkynes via the combination of photoredox and nickel catalysis
description	Converting alkynes into alkenes with high stereoselectivity via two consecutive C-C bond forming steps is a desirable process, yet very challenging. Here, the authors describe a dual photoredox-nickel catalytic system for the regio- and syn-selective alkylarylation of terminal alkynes with alkyl oxalates and aryl bromides.
format	article
author	Lei Guo Fan Song Shengqing Zhu Huan Li Lingling Chu
author_facet	Lei Guo Fan Song Shengqing Zhu Huan Li Lingling Chu
author_sort	Lei Guo
title	syn-Selective alkylarylation of terminal alkynes via the combination of photoredox and nickel catalysis
title_short	syn-Selective alkylarylation of terminal alkynes via the combination of photoredox and nickel catalysis
title_full	syn-Selective alkylarylation of terminal alkynes via the combination of photoredox and nickel catalysis
title_fullStr	syn-Selective alkylarylation of terminal alkynes via the combination of photoredox and nickel catalysis
title_full_unstemmed	syn-Selective alkylarylation of terminal alkynes via the combination of photoredox and nickel catalysis
title_sort	syn-selective alkylarylation of terminal alkynes via the combination of photoredox and nickel catalysis
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/c4f51708a4e34e558cb4dc711bb94cf0
work_keys_str_mv	AT leiguo synselectivealkylarylationofterminalalkynesviathecombinationofphotoredoxandnickelcatalysis AT fansong synselectivealkylarylationofterminalalkynesviathecombinationofphotoredoxandnickelcatalysis AT shengqingzhu synselectivealkylarylationofterminalalkynesviathecombinationofphotoredoxandnickelcatalysis AT huanli synselectivealkylarylationofterminalalkynesviathecombinationofphotoredoxandnickelcatalysis AT linglingchu synselectivealkylarylationofterminalalkynesviathecombinationofphotoredoxandnickelcatalysis
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syn-Selective alkylarylation of terminal alkynes via the combination of photoredox and nickel catalysis

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