Direct and selective access to amino-poly(phenylene vinylenes)s with switchable properties by dimerizing polymerization of aminoaryl carbenes

Despite the ubiquity of singlet carbenes in chemistry, their utility as true monomeric building blocks for the synthesis of functional organic polymers has been underexplored. Here the authors show mono- and bis-acyclic amino(aryl)carbenes selectively dimerize to form diaminoalkenes and hitherto unk...

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Autores principales:	Quentin Sobczak, Aravindu Kunche, Damien Magis, Daiann Sosa Carrizo, Karinne Miqueu, Jean-Marc Sotiropoulos, Eric Cloutet, Cyril Brochon, Yannick Landais, Daniel Taton, Joan Vignolle
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/c5343cc396124d708a8045281a5ca51d
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spelling	oai:doaj.org-article:c5343cc396124d708a8045281a5ca51d2021-12-02T16:10:51ZDirect and selective access to amino-poly(phenylene vinylenes)s with switchable properties by dimerizing polymerization of aminoaryl carbenes10.1038/s41467-021-24274-72041-1723https://doaj.org/article/c5343cc396124d708a8045281a5ca51d2021-07-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-24274-7https://doaj.org/toc/2041-1723Despite the ubiquity of singlet carbenes in chemistry, their utility as true monomeric building blocks for the synthesis of functional organic polymers has been underexplored. Here the authors show mono- and bis-acyclic amino(aryl)carbenes selectively dimerize to form diaminoalkenes and hitherto unknown amino-containing poly(p-phenylene vinylene)s.Quentin SobczakAravindu KuncheDamien MagisDaiann Sosa CarrizoKarinne MiqueuJean-Marc SotiropoulosEric CloutetCyril BrochonYannick LandaisDaniel TatonJoan VignolleNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-8 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Quentin Sobczak Aravindu Kunche Damien Magis Daiann Sosa Carrizo Karinne Miqueu Jean-Marc Sotiropoulos Eric Cloutet Cyril Brochon Yannick Landais Daniel Taton Joan Vignolle Direct and selective access to amino-poly(phenylene vinylenes)s with switchable properties by dimerizing polymerization of aminoaryl carbenes
description	Despite the ubiquity of singlet carbenes in chemistry, their utility as true monomeric building blocks for the synthesis of functional organic polymers has been underexplored. Here the authors show mono- and bis-acyclic amino(aryl)carbenes selectively dimerize to form diaminoalkenes and hitherto unknown amino-containing poly(p-phenylene vinylene)s.
format	article
author	Quentin Sobczak Aravindu Kunche Damien Magis Daiann Sosa Carrizo Karinne Miqueu Jean-Marc Sotiropoulos Eric Cloutet Cyril Brochon Yannick Landais Daniel Taton Joan Vignolle
author_facet	Quentin Sobczak Aravindu Kunche Damien Magis Daiann Sosa Carrizo Karinne Miqueu Jean-Marc Sotiropoulos Eric Cloutet Cyril Brochon Yannick Landais Daniel Taton Joan Vignolle
author_sort	Quentin Sobczak
title	Direct and selective access to amino-poly(phenylene vinylenes)s with switchable properties by dimerizing polymerization of aminoaryl carbenes
title_short	Direct and selective access to amino-poly(phenylene vinylenes)s with switchable properties by dimerizing polymerization of aminoaryl carbenes
title_full	Direct and selective access to amino-poly(phenylene vinylenes)s with switchable properties by dimerizing polymerization of aminoaryl carbenes
title_fullStr	Direct and selective access to amino-poly(phenylene vinylenes)s with switchable properties by dimerizing polymerization of aminoaryl carbenes
title_full_unstemmed	Direct and selective access to amino-poly(phenylene vinylenes)s with switchable properties by dimerizing polymerization of aminoaryl carbenes
title_sort	direct and selective access to amino-poly(phenylene vinylenes)s with switchable properties by dimerizing polymerization of aminoaryl carbenes
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/c5343cc396124d708a8045281a5ca51d
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Direct and selective access to amino-poly(phenylene vinylenes)s with switchable properties by dimerizing polymerization of aminoaryl carbenes

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