Direct and selective access to amino-poly(phenylene vinylenes)s with switchable properties by dimerizing polymerization of aminoaryl carbenes

Despite the ubiquity of singlet carbenes in chemistry, their utility as true monomeric building blocks for the synthesis of functional organic polymers has been underexplored. Here the authors show mono- and bis-acyclic amino(aryl)carbenes selectively dimerize to form diaminoalkenes and hitherto unk...

Full description

Saved in:

Bibliographic Details
Main Authors:	Quentin Sobczak, Aravindu Kunche, Damien Magis, Daiann Sosa Carrizo, Karinne Miqueu, Jean-Marc Sotiropoulos, Eric Cloutet, Cyril Brochon, Yannick Landais, Daniel Taton, Joan Vignolle
Format:	article
Language:	EN
Published:	Nature Portfolio 2021
Subjects:	Science Q
Online Access:	https://doaj.org/article/c5343cc396124d708a8045281a5ca51d
Tags:	Add Tag No Tags, Be the first to tag this record!

id	oai:doaj.org-article:c5343cc396124d708a8045281a5ca51d
record_format	dspace
spelling	oai:doaj.org-article:c5343cc396124d708a8045281a5ca51d2021-12-02T16:10:51ZDirect and selective access to amino-poly(phenylene vinylenes)s with switchable properties by dimerizing polymerization of aminoaryl carbenes10.1038/s41467-021-24274-72041-1723https://doaj.org/article/c5343cc396124d708a8045281a5ca51d2021-07-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-24274-7https://doaj.org/toc/2041-1723Despite the ubiquity of singlet carbenes in chemistry, their utility as true monomeric building blocks for the synthesis of functional organic polymers has been underexplored. Here the authors show mono- and bis-acyclic amino(aryl)carbenes selectively dimerize to form diaminoalkenes and hitherto unknown amino-containing poly(p-phenylene vinylene)s.Quentin SobczakAravindu KuncheDamien MagisDaiann Sosa CarrizoKarinne MiqueuJean-Marc SotiropoulosEric CloutetCyril BrochonYannick LandaisDaniel TatonJoan VignolleNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-8 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Quentin Sobczak Aravindu Kunche Damien Magis Daiann Sosa Carrizo Karinne Miqueu Jean-Marc Sotiropoulos Eric Cloutet Cyril Brochon Yannick Landais Daniel Taton Joan Vignolle Direct and selective access to amino-poly(phenylene vinylenes)s with switchable properties by dimerizing polymerization of aminoaryl carbenes
description	Despite the ubiquity of singlet carbenes in chemistry, their utility as true monomeric building blocks for the synthesis of functional organic polymers has been underexplored. Here the authors show mono- and bis-acyclic amino(aryl)carbenes selectively dimerize to form diaminoalkenes and hitherto unknown amino-containing poly(p-phenylene vinylene)s.
format	article
author	Quentin Sobczak Aravindu Kunche Damien Magis Daiann Sosa Carrizo Karinne Miqueu Jean-Marc Sotiropoulos Eric Cloutet Cyril Brochon Yannick Landais Daniel Taton Joan Vignolle
author_facet	Quentin Sobczak Aravindu Kunche Damien Magis Daiann Sosa Carrizo Karinne Miqueu Jean-Marc Sotiropoulos Eric Cloutet Cyril Brochon Yannick Landais Daniel Taton Joan Vignolle
author_sort	Quentin Sobczak
title	Direct and selective access to amino-poly(phenylene vinylenes)s with switchable properties by dimerizing polymerization of aminoaryl carbenes
title_short	Direct and selective access to amino-poly(phenylene vinylenes)s with switchable properties by dimerizing polymerization of aminoaryl carbenes
title_full	Direct and selective access to amino-poly(phenylene vinylenes)s with switchable properties by dimerizing polymerization of aminoaryl carbenes
title_fullStr	Direct and selective access to amino-poly(phenylene vinylenes)s with switchable properties by dimerizing polymerization of aminoaryl carbenes
title_full_unstemmed	Direct and selective access to amino-poly(phenylene vinylenes)s with switchable properties by dimerizing polymerization of aminoaryl carbenes
title_sort	direct and selective access to amino-poly(phenylene vinylenes)s with switchable properties by dimerizing polymerization of aminoaryl carbenes
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/c5343cc396124d708a8045281a5ca51d
work_keys_str_mv	AT quentinsobczak directandselectiveaccesstoaminopolyphenylenevinylenesswithswitchablepropertiesbydimerizingpolymerizationofaminoarylcarbenes AT aravindukunche directandselectiveaccesstoaminopolyphenylenevinylenesswithswitchablepropertiesbydimerizingpolymerizationofaminoarylcarbenes AT damienmagis directandselectiveaccesstoaminopolyphenylenevinylenesswithswitchablepropertiesbydimerizingpolymerizationofaminoarylcarbenes AT daiannsosacarrizo directandselectiveaccesstoaminopolyphenylenevinylenesswithswitchablepropertiesbydimerizingpolymerizationofaminoarylcarbenes AT karinnemiqueu directandselectiveaccesstoaminopolyphenylenevinylenesswithswitchablepropertiesbydimerizingpolymerizationofaminoarylcarbenes AT jeanmarcsotiropoulos directandselectiveaccesstoaminopolyphenylenevinylenesswithswitchablepropertiesbydimerizingpolymerizationofaminoarylcarbenes AT ericcloutet directandselectiveaccesstoaminopolyphenylenevinylenesswithswitchablepropertiesbydimerizingpolymerizationofaminoarylcarbenes AT cyrilbrochon directandselectiveaccesstoaminopolyphenylenevinylenesswithswitchablepropertiesbydimerizingpolymerizationofaminoarylcarbenes AT yannicklandais directandselectiveaccesstoaminopolyphenylenevinylenesswithswitchablepropertiesbydimerizingpolymerizationofaminoarylcarbenes AT danieltaton directandselectiveaccesstoaminopolyphenylenevinylenesswithswitchablepropertiesbydimerizingpolymerizationofaminoarylcarbenes AT joanvignolle directandselectiveaccesstoaminopolyphenylenevinylenesswithswitchablepropertiesbydimerizingpolymerizationofaminoarylcarbenes
_version_	1718384436932771840

Direct and selective access to amino-poly(phenylene vinylenes)s with switchable properties by dimerizing polymerization of aminoaryl carbenes

Similar Items