A modest method of synthesis Cu- based metal-organic frameworks using benzene dicarbocxylate as a ligan for promising candidate of flue gas CO2 adsorption

Metal organic framework (MOF) is one of extraordinary materials in many technical field applications. One of them is as CO2 gas adsorbent. We studied, synthesized, and characterized Copper-based material, known as Metal organic frameworks (MOFs), using a solvothermal-based modification method. Coppe...

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Autores principales:	MUTTAQIN MUTTAQIN, FARID IMAM HIDAYAT
Formato:	article
Lenguaje:	EN
Publicado:	Universitas Syiah Kuala 2021
Materias:	mmetal organic framework, ccs, cubdc, adsorbent Science (General) Q1-390
Acceso en línea:	https://doaj.org/article/c56c2e3fb4e24e2195e7972a7b019cf7
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spelling	oai:doaj.org-article:c56c2e3fb4e24e2195e7972a7b019cf72021-11-18T07:51:52ZA modest method of synthesis Cu- based metal-organic frameworks using benzene dicarbocxylate as a ligan for promising candidate of flue gas CO2 adsorption1411-85132541-406210.24815/jn.v21i3.20035https://doaj.org/article/c56c2e3fb4e24e2195e7972a7b019cf72021-10-01T00:00:00Zhttp://jurnal.unsyiah.ac.id/natural/article/view/20035https://doaj.org/toc/1411-8513https://doaj.org/toc/2541-4062Metal organic framework (MOF) is one of extraordinary materials in many technical field applications. One of them is as CO2 gas adsorbent. We studied, synthesized, and characterized Copper-based material, known as Metal organic frameworks (MOFs), using a solvothermal-based modification method. Copper salt (Cu (NO3)2. 3H2O) and benzene dicarboxylic acid (H2BDC) were mixed and then heated in an oven at 120°C, to produce low impurities, small pore and uniform particle size of materials called CuBDC. Infrared spectroscopy and XRD data confirmed the formation of CuBDC. Furthermore, the result showed that CuBDC frameworks have good thermal stability up to 330°C. Thereafter SEM picture showed random, layered, and asymmetrical corners structure which is typical of triclinic crystal system. Lastly, specific surface areas and the porosity were analyzed using The Brunauer-Emmett-Teller (BET) method. It recorded 485 m2.g-1 of surface area while average pore volume and average pore size are 0.16 cm3.g-1 and 5.9 Å respectively. @font-face {font-family:"Cambria Math"; panose-1:2 4 5 3 5 4 6 3 2 4; mso-font-charset:0; mso-generic-font-family:roman; mso-font-pitch:variable; mso-font-signature:-536869121 1107305727 33554432 0 415 0;}p.MsoNormal, li.MsoNormal, div.MsoNormal {mso-style-unhide:no; mso-style-qformat:yes; mso-style-parent:""; margin:0cm; mso-pagination:widow-orphan; font-size:12.0pt; font-family:"Times New Roman",serif; mso-fareast-font-family:"Times New Roman"; mso-ansi-language:EN-US;}.MsoChpDefault {mso-style-type:export-only; mso-default-props:yes; font-size:10.0pt; mso-ansi-font-size:10.0pt; mso-bidi-font-size:10.0pt; mso-ansi-language:IN; mso-fareast-language:IN;}div.WordSection1 {page:WordSection1;}MUTTAQIN MUTTAQINFARID IMAM HIDAYATUniversitas Syiah Kualaarticlemmetal organic framework, ccs, cubdc, adsorbentScience (General)Q1-390ENJurnal Natural, Vol 21, Iss 3, Pp 128-134 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	mmetal organic framework, ccs, cubdc, adsorbent Science (General) Q1-390
spellingShingle	mmetal organic framework, ccs, cubdc, adsorbent Science (General) Q1-390 MUTTAQIN MUTTAQIN FARID IMAM HIDAYAT A modest method of synthesis Cu- based metal-organic frameworks using benzene dicarbocxylate as a ligan for promising candidate of flue gas CO2 adsorption
description	Metal organic framework (MOF) is one of extraordinary materials in many technical field applications. One of them is as CO2 gas adsorbent. We studied, synthesized, and characterized Copper-based material, known as Metal organic frameworks (MOFs), using a solvothermal-based modification method. Copper salt (Cu (NO3)2. 3H2O) and benzene dicarboxylic acid (H2BDC) were mixed and then heated in an oven at 120°C, to produce low impurities, small pore and uniform particle size of materials called CuBDC. Infrared spectroscopy and XRD data confirmed the formation of CuBDC. Furthermore, the result showed that CuBDC frameworks have good thermal stability up to 330°C. Thereafter SEM picture showed random, layered, and asymmetrical corners structure which is typical of triclinic crystal system. Lastly, specific surface areas and the porosity were analyzed using The Brunauer-Emmett-Teller (BET) method. It recorded 485 m2.g-1 of surface area while average pore volume and average pore size are 0.16 cm3.g-1 and 5.9 Å respectively. @font-face {font-family:"Cambria Math"; panose-1:2 4 5 3 5 4 6 3 2 4; mso-font-charset:0; mso-generic-font-family:roman; mso-font-pitch:variable; mso-font-signature:-536869121 1107305727 33554432 0 415 0;}p.MsoNormal, li.MsoNormal, div.MsoNormal {mso-style-unhide:no; mso-style-qformat:yes; mso-style-parent:""; margin:0cm; mso-pagination:widow-orphan; font-size:12.0pt; font-family:"Times New Roman",serif; mso-fareast-font-family:"Times New Roman"; mso-ansi-language:EN-US;}.MsoChpDefault {mso-style-type:export-only; mso-default-props:yes; font-size:10.0pt; mso-ansi-font-size:10.0pt; mso-bidi-font-size:10.0pt; mso-ansi-language:IN; mso-fareast-language:IN;}div.WordSection1 {page:WordSection1;}
format	article
author	MUTTAQIN MUTTAQIN FARID IMAM HIDAYAT
author_facet	MUTTAQIN MUTTAQIN FARID IMAM HIDAYAT
author_sort	MUTTAQIN MUTTAQIN
title	A modest method of synthesis Cu- based metal-organic frameworks using benzene dicarbocxylate as a ligan for promising candidate of flue gas CO2 adsorption
title_short	A modest method of synthesis Cu- based metal-organic frameworks using benzene dicarbocxylate as a ligan for promising candidate of flue gas CO2 adsorption
title_full	A modest method of synthesis Cu- based metal-organic frameworks using benzene dicarbocxylate as a ligan for promising candidate of flue gas CO2 adsorption
title_fullStr	A modest method of synthesis Cu- based metal-organic frameworks using benzene dicarbocxylate as a ligan for promising candidate of flue gas CO2 adsorption
title_full_unstemmed	A modest method of synthesis Cu- based metal-organic frameworks using benzene dicarbocxylate as a ligan for promising candidate of flue gas CO2 adsorption
title_sort	modest method of synthesis cu- based metal-organic frameworks using benzene dicarbocxylate as a ligan for promising candidate of flue gas co2 adsorption
publisher	Universitas Syiah Kuala
publishDate	2021
url	https://doaj.org/article/c56c2e3fb4e24e2195e7972a7b019cf7
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A modest method of synthesis Cu- based metal-organic frameworks using benzene dicarbocxylate as a ligan for promising candidate of flue gas CO2 adsorption

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