Amplification of chirality in surface-confined supramolecular bilayers

One of the most dramatic effects of supramolecular assembly is the generation of homochirality in near-racemic systems. Here the authors rationalize the chiral amplification mechanism with a combined scanning tunneling microscopy and modelling study of surface-grown enantiomerically unbalanced supra...

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Autores principales: Hai Cao, Steven De Feyter
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2018
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Acceso en línea:https://doaj.org/article/c598270b8cb94561b5277efc78403632
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Sumario:One of the most dramatic effects of supramolecular assembly is the generation of homochirality in near-racemic systems. Here the authors rationalize the chiral amplification mechanism with a combined scanning tunneling microscopy and modelling study of surface-grown enantiomerically unbalanced supramolecular bilayers.