Matrimid-JUC-62 and Matrimid-PCN-250 mixed matrix membranes displaying light-responsive gas separation and beneficial ageing characteristics for CO2/N2 separation

Abstract The performance of two generation-3 light-responsive metal-organic framework (MOF), namely JUC-62 and PCN-250, was investigated in a mixed matrix membrane (MMM) form. Both of them were incorporated inside the matrimid as the polymer matrix. Using our custom-designed membrane testing cell, i...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Nicholaus Prasetya, Anastasia A. Teck, Bradley P. Ladewig
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Medicine R Science Q
Acceso en línea:	https://doaj.org/article/c60c43b59edf413a9b58251248151e20
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:c60c43b59edf413a9b58251248151e20
record_format	dspace
spelling	oai:doaj.org-article:c60c43b59edf413a9b58251248151e202021-12-02T15:08:52ZMatrimid-JUC-62 and Matrimid-PCN-250 mixed matrix membranes displaying light-responsive gas separation and beneficial ageing characteristics for CO2/N2 separation10.1038/s41598-018-21263-72045-2322https://doaj.org/article/c60c43b59edf413a9b58251248151e202018-02-01T00:00:00Zhttps://doi.org/10.1038/s41598-018-21263-7https://doaj.org/toc/2045-2322Abstract The performance of two generation-3 light-responsive metal-organic framework (MOF), namely JUC-62 and PCN-250, was investigated in a mixed matrix membrane (MMM) form. Both of them were incorporated inside the matrimid as the polymer matrix. Using our custom-designed membrane testing cell, it was observed that the MMMs showed up to 9% difference in CO2 permeability between its pristine and UV-irradiated condition. This shows that the light-responsive ability of the light-responsive MOFs could still be maintained. Thus, this finding is applicable in designing a smart material. Apart from that, the MMMs also has the potential to be applied for post-combustion carbon capture. At loadings up to 15 wt%, both CO2 permeability and CO2/N2 ideal selectivity could be significantly improved and surpassed the value exhibited by most of the MOF-matrimid MMM. Lastly the long term performance of the MMM was also evaluated and it was observed that both MMM could maintain their performance up to 1 month with only a slight decrease in CO2 permeability observed for 10 wt% PCN-250-matrimid. This study then opens up the possibility to fabricate a novel anti-aging multifunctional membrane material that is applicable as a smart material and also in post combustion carbon capture applications.Nicholaus PrasetyaAnastasia A. TeckBradley P. LadewigNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 8, Iss 1, Pp 1-14 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Medicine R Science Q
spellingShingle	Medicine R Science Q Nicholaus Prasetya Anastasia A. Teck Bradley P. Ladewig Matrimid-JUC-62 and Matrimid-PCN-250 mixed matrix membranes displaying light-responsive gas separation and beneficial ageing characteristics for CO2/N2 separation
description	Abstract The performance of two generation-3 light-responsive metal-organic framework (MOF), namely JUC-62 and PCN-250, was investigated in a mixed matrix membrane (MMM) form. Both of them were incorporated inside the matrimid as the polymer matrix. Using our custom-designed membrane testing cell, it was observed that the MMMs showed up to 9% difference in CO2 permeability between its pristine and UV-irradiated condition. This shows that the light-responsive ability of the light-responsive MOFs could still be maintained. Thus, this finding is applicable in designing a smart material. Apart from that, the MMMs also has the potential to be applied for post-combustion carbon capture. At loadings up to 15 wt%, both CO2 permeability and CO2/N2 ideal selectivity could be significantly improved and surpassed the value exhibited by most of the MOF-matrimid MMM. Lastly the long term performance of the MMM was also evaluated and it was observed that both MMM could maintain their performance up to 1 month with only a slight decrease in CO2 permeability observed for 10 wt% PCN-250-matrimid. This study then opens up the possibility to fabricate a novel anti-aging multifunctional membrane material that is applicable as a smart material and also in post combustion carbon capture applications.
format	article
author	Nicholaus Prasetya Anastasia A. Teck Bradley P. Ladewig
author_facet	Nicholaus Prasetya Anastasia A. Teck Bradley P. Ladewig
author_sort	Nicholaus Prasetya
title	Matrimid-JUC-62 and Matrimid-PCN-250 mixed matrix membranes displaying light-responsive gas separation and beneficial ageing characteristics for CO2/N2 separation
title_short	Matrimid-JUC-62 and Matrimid-PCN-250 mixed matrix membranes displaying light-responsive gas separation and beneficial ageing characteristics for CO2/N2 separation
title_full	Matrimid-JUC-62 and Matrimid-PCN-250 mixed matrix membranes displaying light-responsive gas separation and beneficial ageing characteristics for CO2/N2 separation
title_fullStr	Matrimid-JUC-62 and Matrimid-PCN-250 mixed matrix membranes displaying light-responsive gas separation and beneficial ageing characteristics for CO2/N2 separation
title_full_unstemmed	Matrimid-JUC-62 and Matrimid-PCN-250 mixed matrix membranes displaying light-responsive gas separation and beneficial ageing characteristics for CO2/N2 separation
title_sort	matrimid-juc-62 and matrimid-pcn-250 mixed matrix membranes displaying light-responsive gas separation and beneficial ageing characteristics for co2/n2 separation
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/c60c43b59edf413a9b58251248151e20
work_keys_str_mv	AT nicholausprasetya matrimidjuc62andmatrimidpcn250mixedmatrixmembranesdisplayinglightresponsivegasseparationandbeneficialageingcharacteristicsforco2n2separation AT anastasiaateck matrimidjuc62andmatrimidpcn250mixedmatrixmembranesdisplayinglightresponsivegasseparationandbeneficialageingcharacteristicsforco2n2separation AT bradleypladewig matrimidjuc62andmatrimidpcn250mixedmatrixmembranesdisplayinglightresponsivegasseparationandbeneficialageingcharacteristicsforco2n2separation
_version_	1718388026342637568

Matrimid-JUC-62 and Matrimid-PCN-250 mixed matrix membranes displaying light-responsive gas separation and beneficial ageing characteristics for CO2/N2 separation

Ejemplares similares