Dual-emitter polymer carbon dots with spectral selection towards nanomolar detection of iron and aluminum ions

We report on the spectral selection of excitation wavelength towards selective detection of aluminum and iron ions using dual emission polymer carbon dots (PCDs). PCDs were prepared from glucose and dilute sulfuric acid using one-pot solvothermal method. The PCDs emit blue light at 480 nm when excit...

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Autores principales:	Aso Q. Hassan, Ravin K. Barzani, Khalid M. Omer, Baraa R. Al-Hashimi, Somayeh Mohammadi, Abdollah Salimi
Formato:	article
Lenguaje:	EN
Publicado:	Elsevier 2021
Materias:	Polymer carbon dots Dual emissive fluorescence probe Tablets analysis Cancer cell bioimaging Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/c68e67261b5a4319951691ca7f6be025
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spelling	oai:doaj.org-article:c68e67261b5a4319951691ca7f6be0252021-11-20T04:58:11ZDual-emitter polymer carbon dots with spectral selection towards nanomolar detection of iron and aluminum ions1878-535210.1016/j.arabjc.2021.103452https://doaj.org/article/c68e67261b5a4319951691ca7f6be0252021-12-01T00:00:00Zhttp://www.sciencedirect.com/science/article/pii/S1878535221004676https://doaj.org/toc/1878-5352We report on the spectral selection of excitation wavelength towards selective detection of aluminum and iron ions using dual emission polymer carbon dots (PCDs). PCDs were prepared from glucose and dilute sulfuric acid using one-pot solvothermal method. The PCDs emit blue light at 480 nm when excited at 340 nm, while emit red light at 590 nm when excited with 400 nm. Spectral selection (selection of excited state) showed sensitivity enhancement for detection of some metal ions. The PCDs showed fluorescence enhancement when combined with Al3+ ions with hypsochromic shift centered at 470 nm when excited at 440 nm. While the PCDs selectively quenched via addition of Fe3+ ions, when excited at 400 nm. The wavelength selection of the same carbon dots increases signal to noise ration. The PCDs showed thermo-sensing behavior from 0 °C to 90 °C with reasonably good reversibility. The PCDs acted as fluorescent probes for multicolor (green and yellow) imaging of MCF-7 cells while not inducing cell death, which indicates that the PCDs are biocompatible and nontoxic to the cells. Therefore, the PCDs can be used as probes for cell-imaging applications in vitro and in vivo. The PCDs proved to be a multi-purpose polymer carbon nanomaterial that can used for pharmaceutical analysis, bio-imaging and thermo-sensing while providing high accuracy, selectivity and a limit of detection in the nano range.Aso Q. HassanRavin K. BarzaniKhalid M. OmerBaraa R. Al-HashimiSomayeh MohammadiAbdollah SalimiElsevierarticlePolymer carbon dotsDual emissive fluorescence probeTablets analysisCancer cell bioimagingChemistryQD1-999ENArabian Journal of Chemistry, Vol 14, Iss 12, Pp 103452- (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Polymer carbon dots Dual emissive fluorescence probe Tablets analysis Cancer cell bioimaging Chemistry QD1-999
spellingShingle	Polymer carbon dots Dual emissive fluorescence probe Tablets analysis Cancer cell bioimaging Chemistry QD1-999 Aso Q. Hassan Ravin K. Barzani Khalid M. Omer Baraa R. Al-Hashimi Somayeh Mohammadi Abdollah Salimi Dual-emitter polymer carbon dots with spectral selection towards nanomolar detection of iron and aluminum ions
description	We report on the spectral selection of excitation wavelength towards selective detection of aluminum and iron ions using dual emission polymer carbon dots (PCDs). PCDs were prepared from glucose and dilute sulfuric acid using one-pot solvothermal method. The PCDs emit blue light at 480 nm when excited at 340 nm, while emit red light at 590 nm when excited with 400 nm. Spectral selection (selection of excited state) showed sensitivity enhancement for detection of some metal ions. The PCDs showed fluorescence enhancement when combined with Al3+ ions with hypsochromic shift centered at 470 nm when excited at 440 nm. While the PCDs selectively quenched via addition of Fe3+ ions, when excited at 400 nm. The wavelength selection of the same carbon dots increases signal to noise ration. The PCDs showed thermo-sensing behavior from 0 °C to 90 °C with reasonably good reversibility. The PCDs acted as fluorescent probes for multicolor (green and yellow) imaging of MCF-7 cells while not inducing cell death, which indicates that the PCDs are biocompatible and nontoxic to the cells. Therefore, the PCDs can be used as probes for cell-imaging applications in vitro and in vivo. The PCDs proved to be a multi-purpose polymer carbon nanomaterial that can used for pharmaceutical analysis, bio-imaging and thermo-sensing while providing high accuracy, selectivity and a limit of detection in the nano range.
format	article
author	Aso Q. Hassan Ravin K. Barzani Khalid M. Omer Baraa R. Al-Hashimi Somayeh Mohammadi Abdollah Salimi
author_facet	Aso Q. Hassan Ravin K. Barzani Khalid M. Omer Baraa R. Al-Hashimi Somayeh Mohammadi Abdollah Salimi
author_sort	Aso Q. Hassan
title	Dual-emitter polymer carbon dots with spectral selection towards nanomolar detection of iron and aluminum ions
title_short	Dual-emitter polymer carbon dots with spectral selection towards nanomolar detection of iron and aluminum ions
title_full	Dual-emitter polymer carbon dots with spectral selection towards nanomolar detection of iron and aluminum ions
title_fullStr	Dual-emitter polymer carbon dots with spectral selection towards nanomolar detection of iron and aluminum ions
title_full_unstemmed	Dual-emitter polymer carbon dots with spectral selection towards nanomolar detection of iron and aluminum ions
title_sort	dual-emitter polymer carbon dots with spectral selection towards nanomolar detection of iron and aluminum ions
publisher	Elsevier
publishDate	2021
url	https://doaj.org/article/c68e67261b5a4319951691ca7f6be025
work_keys_str_mv	AT asoqhassan dualemitterpolymercarbondotswithspectralselectiontowardsnanomolardetectionofironandaluminumions AT ravinkbarzani dualemitterpolymercarbondotswithspectralselectiontowardsnanomolardetectionofironandaluminumions AT khalidmomer dualemitterpolymercarbondotswithspectralselectiontowardsnanomolardetectionofironandaluminumions AT baraaralhashimi dualemitterpolymercarbondotswithspectralselectiontowardsnanomolardetectionofironandaluminumions AT somayehmohammadi dualemitterpolymercarbondotswithspectralselectiontowardsnanomolardetectionofironandaluminumions AT abdollahsalimi dualemitterpolymercarbondotswithspectralselectiontowardsnanomolardetectionofironandaluminumions
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Dual-emitter polymer carbon dots with spectral selection towards nanomolar detection of iron and aluminum ions

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