Two-dimensional lithium diffusion behavior and probable hybrid phase transformation kinetics in olivine lithium iron phosphate

Lithium transport and phase transformation kinetics in olivine LiFePO4 electrode remain not fully understood. Here the authors show that microsized olivine particles possess 2D lithium diffusivity and exhibit a possible hybrid mode of phase boundary migration upon cycling.

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Detalles Bibliográficos
Autores principales: Liang Hong, Linsen Li, Yuchen-Karen Chen-Wiegart, Jiajun Wang, Kai Xiang, Liyang Gan, Wenjie Li, Fei Meng, Fan Wang, Jun Wang, Yet-Ming Chiang, Song Jin, Ming Tang
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/c69b5714526d4334beb16800bed091ca
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Sumario:Lithium transport and phase transformation kinetics in olivine LiFePO4 electrode remain not fully understood. Here the authors show that microsized olivine particles possess 2D lithium diffusivity and exhibit a possible hybrid mode of phase boundary migration upon cycling.