Energetics of Baird aromaticity supported by inversion of photoexcited chiral [4n]annulene derivatives

Baird’s rule applies to cyclic π-conjugated molecules in their excited state, yet a quantification of the involved energetics is elusive. Here, the authors show the ring inversion kinetics of two nonplanar and chiral [4n]annulenes to support Baird’s rule from an energetic point of view.

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Autores principales:	Michihisa Ueda, Kjell Jorner, Young Mo Sung, Tadashi Mori, Qi Xiao, Dongho Kim, Henrik Ottosson, Takuzo Aida, Yoshimitsu Itoh
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2017
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/c6add6e0a20c4c13ab7a1fd6ca022d7b
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spelling	oai:doaj.org-article:c6add6e0a20c4c13ab7a1fd6ca022d7b2021-12-02T14:42:01ZEnergetics of Baird aromaticity supported by inversion of photoexcited chiral [4n]annulene derivatives10.1038/s41467-017-00382-12041-1723https://doaj.org/article/c6add6e0a20c4c13ab7a1fd6ca022d7b2017-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-00382-1https://doaj.org/toc/2041-1723Baird’s rule applies to cyclic π-conjugated molecules in their excited state, yet a quantification of the involved energetics is elusive. Here, the authors show the ring inversion kinetics of two nonplanar and chiral [4n]annulenes to support Baird’s rule from an energetic point of view.Michihisa UedaKjell JornerYoung Mo SungTadashi MoriQi XiaoDongho KimHenrik OttossonTakuzo AidaYoshimitsu ItohNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-9 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Michihisa Ueda Kjell Jorner Young Mo Sung Tadashi Mori Qi Xiao Dongho Kim Henrik Ottosson Takuzo Aida Yoshimitsu Itoh Energetics of Baird aromaticity supported by inversion of photoexcited chiral [4n]annulene derivatives
description	Baird’s rule applies to cyclic π-conjugated molecules in their excited state, yet a quantification of the involved energetics is elusive. Here, the authors show the ring inversion kinetics of two nonplanar and chiral [4n]annulenes to support Baird’s rule from an energetic point of view.
format	article
author	Michihisa Ueda Kjell Jorner Young Mo Sung Tadashi Mori Qi Xiao Dongho Kim Henrik Ottosson Takuzo Aida Yoshimitsu Itoh
author_facet	Michihisa Ueda Kjell Jorner Young Mo Sung Tadashi Mori Qi Xiao Dongho Kim Henrik Ottosson Takuzo Aida Yoshimitsu Itoh
author_sort	Michihisa Ueda
title	Energetics of Baird aromaticity supported by inversion of photoexcited chiral [4n]annulene derivatives
title_short	Energetics of Baird aromaticity supported by inversion of photoexcited chiral [4n]annulene derivatives
title_full	Energetics of Baird aromaticity supported by inversion of photoexcited chiral [4n]annulene derivatives
title_fullStr	Energetics of Baird aromaticity supported by inversion of photoexcited chiral [4n]annulene derivatives
title_full_unstemmed	Energetics of Baird aromaticity supported by inversion of photoexcited chiral [4n]annulene derivatives
title_sort	energetics of baird aromaticity supported by inversion of photoexcited chiral [4n]annulene derivatives
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/c6add6e0a20c4c13ab7a1fd6ca022d7b
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Energetics of Baird aromaticity supported by inversion of photoexcited chiral [4n]annulene derivatives

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