Fabrication of Ni–MOF-derived composite material for efficient electrocatalytic OER

The poverty-stricken population cannot withstand the shocks of global warming and can hardly pay the soaring expenditure of fossil fuels whose reservoirs are already approaching the threshold limit. These adventures guided the researchers towards water oxidation as a source of energy. In this study,...

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Autores principales: Muhammad Yousaf ur Rehman, Dilshad Hussain, Sajid Abbas, Ashfaq Mahmood Qureshi, Adeel Hussain Chughtai, Muhammad Najam-Ul-Haq, Abdullah Saad Alsubaie, Sumaira Manzoor, Khaled H. Mahmoud, Muhammad Naeem Ashiq
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Publicado: Taylor & Francis Group 2021
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spelling oai:doaj.org-article:c704fdcab9794fb4ad7ff687a517335d2021-11-04T15:00:42ZFabrication of Ni–MOF-derived composite material for efficient electrocatalytic OER1658-365510.1080/16583655.2021.1996944https://doaj.org/article/c704fdcab9794fb4ad7ff687a517335d2021-01-01T00:00:00Zhttp://dx.doi.org/10.1080/16583655.2021.1996944https://doaj.org/toc/1658-3655The poverty-stricken population cannot withstand the shocks of global warming and can hardly pay the soaring expenditure of fossil fuels whose reservoirs are already approaching the threshold limit. These adventures guided the researchers towards water oxidation as a source of energy. In this study, a metal-organic framework (MOF)-based material was fabricated and catalyzed the lethargic oxygen evolution reaction (OER). The synthesized material is characterized with different analytical techniques to confirm structural, morphological and textural properties. Its huge surface area (87 m2/g) rendered it a promising material to carry the OER. It exhibited shallow onset potential that is, 1.40 V vs. RHE and displayed an exceptionally low overpotential of 1.42 V vs. RHE to reach the benchmark current density (10 mA/cm2) with remarkably small Tafel slope that is, 34 mV/dec. It surpassed the state of the art electrocatalyst for OER, that is, IrO2 and RuO2 in efficiency as well as in stability.Muhammad Yousaf ur RehmanDilshad HussainSajid AbbasAshfaq Mahmood QureshiAdeel Hussain ChughtaiMuhammad Najam-Ul-HaqAbdullah Saad AlsubaieSumaira ManzoorKhaled H. MahmoudMuhammad Naeem AshiqTaylor & Francis Grouparticlecarbon dotsni–mof-derived compositecatalytic siteselectrochemical characterizationsoxygen evolution reactionScience (General)Q1-390ENJournal of Taibah University for Science, Vol 15, Iss 1, Pp 637-648 (2021)
institution DOAJ
collection DOAJ
language EN
topic carbon dots
ni–mof-derived composite
catalytic sites
electrochemical characterizations
oxygen evolution reaction
Science (General)
Q1-390
spellingShingle carbon dots
ni–mof-derived composite
catalytic sites
electrochemical characterizations
oxygen evolution reaction
Science (General)
Q1-390
Muhammad Yousaf ur Rehman
Dilshad Hussain
Sajid Abbas
Ashfaq Mahmood Qureshi
Adeel Hussain Chughtai
Muhammad Najam-Ul-Haq
Abdullah Saad Alsubaie
Sumaira Manzoor
Khaled H. Mahmoud
Muhammad Naeem Ashiq
Fabrication of Ni–MOF-derived composite material for efficient electrocatalytic OER
description The poverty-stricken population cannot withstand the shocks of global warming and can hardly pay the soaring expenditure of fossil fuels whose reservoirs are already approaching the threshold limit. These adventures guided the researchers towards water oxidation as a source of energy. In this study, a metal-organic framework (MOF)-based material was fabricated and catalyzed the lethargic oxygen evolution reaction (OER). The synthesized material is characterized with different analytical techniques to confirm structural, morphological and textural properties. Its huge surface area (87 m2/g) rendered it a promising material to carry the OER. It exhibited shallow onset potential that is, 1.40 V vs. RHE and displayed an exceptionally low overpotential of 1.42 V vs. RHE to reach the benchmark current density (10 mA/cm2) with remarkably small Tafel slope that is, 34 mV/dec. It surpassed the state of the art electrocatalyst for OER, that is, IrO2 and RuO2 in efficiency as well as in stability.
format article
author Muhammad Yousaf ur Rehman
Dilshad Hussain
Sajid Abbas
Ashfaq Mahmood Qureshi
Adeel Hussain Chughtai
Muhammad Najam-Ul-Haq
Abdullah Saad Alsubaie
Sumaira Manzoor
Khaled H. Mahmoud
Muhammad Naeem Ashiq
author_facet Muhammad Yousaf ur Rehman
Dilshad Hussain
Sajid Abbas
Ashfaq Mahmood Qureshi
Adeel Hussain Chughtai
Muhammad Najam-Ul-Haq
Abdullah Saad Alsubaie
Sumaira Manzoor
Khaled H. Mahmoud
Muhammad Naeem Ashiq
author_sort Muhammad Yousaf ur Rehman
title Fabrication of Ni–MOF-derived composite material for efficient electrocatalytic OER
title_short Fabrication of Ni–MOF-derived composite material for efficient electrocatalytic OER
title_full Fabrication of Ni–MOF-derived composite material for efficient electrocatalytic OER
title_fullStr Fabrication of Ni–MOF-derived composite material for efficient electrocatalytic OER
title_full_unstemmed Fabrication of Ni–MOF-derived composite material for efficient electrocatalytic OER
title_sort fabrication of ni–mof-derived composite material for efficient electrocatalytic oer
publisher Taylor & Francis Group
publishDate 2021
url https://doaj.org/article/c704fdcab9794fb4ad7ff687a517335d
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