Flexible Tellurium-Based Electrode for High-Performance Lithium-Tellurium Battery

Low-dimensional nanomaterials have attracted considerable attention for next-generation flexible energy devices owing to their excellent electrochemical properties and superior flexibility. Herein, uniform Tellurium nanotubes (Te NTs) were prepared through a facile hydrothermal method, and then a fl...

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Autores principales: Yan Li, Ye Zhang
Formato: article
Lenguaje:EN
Publicado: MDPI AG 2021
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Acceso en línea:https://doaj.org/article/c7f161c88a8e4938ac469ed029b77b89
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Sumario:Low-dimensional nanomaterials have attracted considerable attention for next-generation flexible energy devices owing to their excellent electrochemical properties and superior flexibility. Herein, uniform Tellurium nanotubes (Te NTs) were prepared through a facile hydrothermal method, and then a flexible and freestanding electrode was fabricated with Te NTs as active materials and a small amount of nanofibrillated celluloses (NFCs) as a flexible matrix through a vacuum filtration method without adding extra conductive carbon or a binder. The resulting Te-based electrode exhibits a high volumetric capacity of 1512 mAh cm<sup>−3</sup> at 200 mA g<sup>−1</sup>, and delivers admirable cyclic stability (capacity retention of 104% over 300 cycles) and excellent rate performance (833 mAh cm<sup>−3</sup> at 1000 mA g<sup>−1</sup>), which benefits from the unique structure and intrinsically superior conductivity of Te NTs. After bending 50 times, the Te-based electrode delivers a desirable volumetric capacity of 1117 mAh cm<sup>−3</sup>, and remains 93% of initial capacity after 100 cycles. The results imply that the Te-based electrode exhibits excellent electrochemical properties and superior flexibility simultaneously, which can serve as a potential candidate for the flexible lithium batteries.