Emphasis of some physical and dynamical properties of inverted barium phosphate base glass
Melt-annealed zinc barium phosphate invert glass was produced. A mixture of borate (B2O3), cadmium oxide (CdO), and lead oxide (PbO) was added to the synthesized glass. B2O3 in the base glass formed P–O–B linkages with BO3 and BO4 structural units, with CdO acting as a modifier. PbO4 structural unit...
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2021
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oai:doaj.org-article:c8e42dc985af40ea9c190bd631ebae732021-11-06T04:29:45ZEmphasis of some physical and dynamical properties of inverted barium phosphate base glass2238-785410.1016/j.jmrt.2021.10.113https://doaj.org/article/c8e42dc985af40ea9c190bd631ebae732021-11-01T00:00:00Zhttp://www.sciencedirect.com/science/article/pii/S2238785421012461https://doaj.org/toc/2238-7854Melt-annealed zinc barium phosphate invert glass was produced. A mixture of borate (B2O3), cadmium oxide (CdO), and lead oxide (PbO) was added to the synthesized glass. B2O3 in the base glass formed P–O–B linkages with BO3 and BO4 structural units, with CdO acting as a modifier. PbO4 structural units were observed next to PO4 network formers. Glass density (ρ) is affected by doping type and ratio. It was 3.43 g/cm3 for PbO glass and 3.31 g/cm3 for B2O3 glass. The optical properties of the examined glass were measured and discussed in relation to the structural modification of the host glass. The glass sample containing PbO had a high value of Eg at 4.23 eV, but the glass doped with CdO + PbO had a low value at 3.81 eV, depending on the role of the additive in the glass structure. PbO-containing glass had a high damping ratio (7.308%), second only to CdO-containing glass at 8.069%. However, the dynamic Young's modulus of PbO-containing glass was reduced by 25% compared to the base invert glass.Ahmed H. HammadEssam B. MoustafaAhmed R. WasselElsevierarticleInvert phosphate glassStructureOptical propertiesDynamical propertiesMining engineering. MetallurgyTN1-997ENJournal of Materials Research and Technology, Vol 15, Iss , Pp 4813-4825 (2021) |
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Invert phosphate glass Structure Optical properties Dynamical properties Mining engineering. Metallurgy TN1-997 |
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Invert phosphate glass Structure Optical properties Dynamical properties Mining engineering. Metallurgy TN1-997 Ahmed H. Hammad Essam B. Moustafa Ahmed R. Wassel Emphasis of some physical and dynamical properties of inverted barium phosphate base glass |
description |
Melt-annealed zinc barium phosphate invert glass was produced. A mixture of borate (B2O3), cadmium oxide (CdO), and lead oxide (PbO) was added to the synthesized glass. B2O3 in the base glass formed P–O–B linkages with BO3 and BO4 structural units, with CdO acting as a modifier. PbO4 structural units were observed next to PO4 network formers. Glass density (ρ) is affected by doping type and ratio. It was 3.43 g/cm3 for PbO glass and 3.31 g/cm3 for B2O3 glass. The optical properties of the examined glass were measured and discussed in relation to the structural modification of the host glass. The glass sample containing PbO had a high value of Eg at 4.23 eV, but the glass doped with CdO + PbO had a low value at 3.81 eV, depending on the role of the additive in the glass structure. PbO-containing glass had a high damping ratio (7.308%), second only to CdO-containing glass at 8.069%. However, the dynamic Young's modulus of PbO-containing glass was reduced by 25% compared to the base invert glass. |
format |
article |
author |
Ahmed H. Hammad Essam B. Moustafa Ahmed R. Wassel |
author_facet |
Ahmed H. Hammad Essam B. Moustafa Ahmed R. Wassel |
author_sort |
Ahmed H. Hammad |
title |
Emphasis of some physical and dynamical properties of inverted barium phosphate base glass |
title_short |
Emphasis of some physical and dynamical properties of inverted barium phosphate base glass |
title_full |
Emphasis of some physical and dynamical properties of inverted barium phosphate base glass |
title_fullStr |
Emphasis of some physical and dynamical properties of inverted barium phosphate base glass |
title_full_unstemmed |
Emphasis of some physical and dynamical properties of inverted barium phosphate base glass |
title_sort |
emphasis of some physical and dynamical properties of inverted barium phosphate base glass |
publisher |
Elsevier |
publishDate |
2021 |
url |
https://doaj.org/article/c8e42dc985af40ea9c190bd631ebae73 |
work_keys_str_mv |
AT ahmedhhammad emphasisofsomephysicalanddynamicalpropertiesofinvertedbariumphosphatebaseglass AT essambmoustafa emphasisofsomephysicalanddynamicalpropertiesofinvertedbariumphosphatebaseglass AT ahmedrwassel emphasisofsomephysicalanddynamicalpropertiesofinvertedbariumphosphatebaseglass |
_version_ |
1718443882101866496 |