Remote C−H functionalization using radical translocating arylating groups

Selective remote functionalization of aliphatic C(sp3)−H bonds is highly challenging and often requires transition metals and/or directing groups. Here, the authors show the γ-arylation of aliphatic alcohols via a two-step radical translocation and subsequent radical aryl migration.

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Autores principales:	Florian W. Friese, Christian Mück-Lichtenfeld, Armido Studer
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/c959adcc6ac248cb8f072d3ca84f24a4
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spelling	oai:doaj.org-article:c959adcc6ac248cb8f072d3ca84f24a42021-12-02T14:39:43ZRemote C−H functionalization using radical translocating arylating groups10.1038/s41467-018-05193-62041-1723https://doaj.org/article/c959adcc6ac248cb8f072d3ca84f24a42018-07-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-05193-6https://doaj.org/toc/2041-1723Selective remote functionalization of aliphatic C(sp3)−H bonds is highly challenging and often requires transition metals and/or directing groups. Here, the authors show the γ-arylation of aliphatic alcohols via a two-step radical translocation and subsequent radical aryl migration.Florian W. FrieseChristian Mück-LichtenfeldArmido StuderNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-7 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Florian W. Friese Christian Mück-Lichtenfeld Armido Studer Remote C−H functionalization using radical translocating arylating groups
description	Selective remote functionalization of aliphatic C(sp3)−H bonds is highly challenging and often requires transition metals and/or directing groups. Here, the authors show the γ-arylation of aliphatic alcohols via a two-step radical translocation and subsequent radical aryl migration.
format	article
author	Florian W. Friese Christian Mück-Lichtenfeld Armido Studer
author_facet	Florian W. Friese Christian Mück-Lichtenfeld Armido Studer
author_sort	Florian W. Friese
title	Remote C−H functionalization using radical translocating arylating groups
title_short	Remote C−H functionalization using radical translocating arylating groups
title_full	Remote C−H functionalization using radical translocating arylating groups
title_fullStr	Remote C−H functionalization using radical translocating arylating groups
title_full_unstemmed	Remote C−H functionalization using radical translocating arylating groups
title_sort	remote c−h functionalization using radical translocating arylating groups
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/c959adcc6ac248cb8f072d3ca84f24a4
work_keys_str_mv	AT florianwfriese remotechfunctionalizationusingradicaltranslocatingarylatinggroups AT christianmucklichtenfeld remotechfunctionalizationusingradicaltranslocatingarylatinggroups AT armidostuder remotechfunctionalizationusingradicaltranslocatingarylatinggroups
_version_	1718390558349590528

Remote C−H functionalization using radical translocating arylating groups

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