Structure-driven CO2 selectivity and gas capacity of ionic clathrate hydrates

Abstract Ionic clathrate hydrates can selectively capture small gas molecules such as CO2, N2, CH4 and H2. We investigated CO2 + N2 mixed gas separation properties of ionic clathrate hydrates formed with tetra-n-butylammonium bromide (TBAB), tetra-n-butylammonium chloride (TBAC), tetra-n-butylphosph...

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Autores principales:	Hidenori Hashimoto, Tsutomu Yamaguchi, Hiroyuki Ozeki, Sanehiro Muromachi
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2017
Materias:	Medicine R Science Q
Acceso en línea:	https://doaj.org/article/c9a5e70d5a33498b98ea87a2d7a35786
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spelling	oai:doaj.org-article:c9a5e70d5a33498b98ea87a2d7a357862021-12-02T15:05:36ZStructure-driven CO2 selectivity and gas capacity of ionic clathrate hydrates10.1038/s41598-017-17375-12045-2322https://doaj.org/article/c9a5e70d5a33498b98ea87a2d7a357862017-12-01T00:00:00Zhttps://doi.org/10.1038/s41598-017-17375-1https://doaj.org/toc/2045-2322Abstract Ionic clathrate hydrates can selectively capture small gas molecules such as CO2, N2, CH4 and H2. We investigated CO2 + N2 mixed gas separation properties of ionic clathrate hydrates formed with tetra-n-butylammonium bromide (TBAB), tetra-n-butylammonium chloride (TBAC), tetra-n-butylphosphonium bromide (TBPB) and tetra-n-butylphosphonium chloride (TBPC). The results showed that CO2 selectivity of TBAC hydrates was remarkably higher than those of the other hydrates despite less gas capacity of TBAC hydrates. The TBAB hydrates also showed irregularly high CO2 selectivity at a low pressure. X-ray diffraction and Raman spectroscopic analyses clarified that TBAC stably formed the tetragonal hydrate structure, and TBPB and TBPC formed the orthorhombic hydrate structure. The TBAB hydrates showed polymorphic phases which may consist of the both orthorhombic and tetragonal hydrate structures. These results showed that the tetragonal hydrate captured CO2 more efficiently than the orthorhombic hydrate, while the orthorhombic hydrate has the largest gas capacity among the basic four structures of ionic clathrate hydrates. The present study suggests new potential for improving gas capacity and selectivity of ionic clathrate hydrates by choosing suitable ionic guest substances for guest gas components.Hidenori HashimotoTsutomu YamaguchiHiroyuki OzekiSanehiro MuromachiNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 7, Iss 1, Pp 1-10 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Medicine R Science Q
spellingShingle	Medicine R Science Q Hidenori Hashimoto Tsutomu Yamaguchi Hiroyuki Ozeki Sanehiro Muromachi Structure-driven CO2 selectivity and gas capacity of ionic clathrate hydrates
description	Abstract Ionic clathrate hydrates can selectively capture small gas molecules such as CO2, N2, CH4 and H2. We investigated CO2 + N2 mixed gas separation properties of ionic clathrate hydrates formed with tetra-n-butylammonium bromide (TBAB), tetra-n-butylammonium chloride (TBAC), tetra-n-butylphosphonium bromide (TBPB) and tetra-n-butylphosphonium chloride (TBPC). The results showed that CO2 selectivity of TBAC hydrates was remarkably higher than those of the other hydrates despite less gas capacity of TBAC hydrates. The TBAB hydrates also showed irregularly high CO2 selectivity at a low pressure. X-ray diffraction and Raman spectroscopic analyses clarified that TBAC stably formed the tetragonal hydrate structure, and TBPB and TBPC formed the orthorhombic hydrate structure. The TBAB hydrates showed polymorphic phases which may consist of the both orthorhombic and tetragonal hydrate structures. These results showed that the tetragonal hydrate captured CO2 more efficiently than the orthorhombic hydrate, while the orthorhombic hydrate has the largest gas capacity among the basic four structures of ionic clathrate hydrates. The present study suggests new potential for improving gas capacity and selectivity of ionic clathrate hydrates by choosing suitable ionic guest substances for guest gas components.
format	article
author	Hidenori Hashimoto Tsutomu Yamaguchi Hiroyuki Ozeki Sanehiro Muromachi
author_facet	Hidenori Hashimoto Tsutomu Yamaguchi Hiroyuki Ozeki Sanehiro Muromachi
author_sort	Hidenori Hashimoto
title	Structure-driven CO2 selectivity and gas capacity of ionic clathrate hydrates
title_short	Structure-driven CO2 selectivity and gas capacity of ionic clathrate hydrates
title_full	Structure-driven CO2 selectivity and gas capacity of ionic clathrate hydrates
title_fullStr	Structure-driven CO2 selectivity and gas capacity of ionic clathrate hydrates
title_full_unstemmed	Structure-driven CO2 selectivity and gas capacity of ionic clathrate hydrates
title_sort	structure-driven co2 selectivity and gas capacity of ionic clathrate hydrates
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/c9a5e70d5a33498b98ea87a2d7a35786
work_keys_str_mv	AT hidenorihashimoto structuredrivenco2selectivityandgascapacityofionicclathratehydrates AT tsutomuyamaguchi structuredrivenco2selectivityandgascapacityofionicclathratehydrates AT hiroyukiozeki structuredrivenco2selectivityandgascapacityofionicclathratehydrates AT sanehiromuromachi structuredrivenco2selectivityandgascapacityofionicclathratehydrates
_version_	1718388792935579648

Structure-driven CO2 selectivity and gas capacity of ionic clathrate hydrates

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