Thermal degradation and pyrolysis kinetic behaviour of glass fibre-reinforced thermoplastic resin by TG-FTIR, Py-GC/MS, linear and nonlinear isoconversional models

Recently, global demand for glass fibre-reinforced thermoplastic (GFRP) composites and their applications in the production of wind turbine blades has increased due to their bigger strength, impact resistance, toughness, etc. compared to thermosetting resin. In this work, the thermal degradation and...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Samy Yousef, Justas Eimontas, Nerijus Striūgas, Sharath P. Subadra, Mohammed Ali Abdelnaby
Formato:	article
Lenguaje:	EN
Publicado:	Elsevier 2021
Materias:	Glass fibre-reinforced polymers Thermoplastic resin Pyrolysis treatment Poly(methyl methacrylate)-PMMA Pyrolysis kinetics Mining engineering. Metallurgy TN1-997
Acceso en línea:	https://doaj.org/article/ca26c49f78344d599ce94acaf3746a89
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:ca26c49f78344d599ce94acaf3746a89
record_format	dspace
spelling	oai:doaj.org-article:ca26c49f78344d599ce94acaf3746a892021-11-20T05:06:38ZThermal degradation and pyrolysis kinetic behaviour of glass fibre-reinforced thermoplastic resin by TG-FTIR, Py-GC/MS, linear and nonlinear isoconversional models2238-785410.1016/j.jmrt.2021.11.011https://doaj.org/article/ca26c49f78344d599ce94acaf3746a892021-11-01T00:00:00Zhttp://www.sciencedirect.com/science/article/pii/S2238785421012904https://doaj.org/toc/2238-7854Recently, global demand for glass fibre-reinforced thermoplastic (GFRP) composites and their applications in the production of wind turbine blades has increased due to their bigger strength, impact resistance, toughness, etc. compared to thermosetting resin. In this work, the thermal degradation and pyrolysis kinetic behaviour of GFRP were studied using TG-FTIR, Py-GC/MS, linear and nonlinear isoconversional models to investigate potential applications in the use of pyrolysis technology in end-of-life GFRP treatment. The experiments were carried out on milled glass fibre/poly(methyl methacrylate)-PMMA composites prepared using the vacuum-assisted resin transfer method and the grinding process. The morphological, ultimate, and proximate properties of the feedstock were observed. The thermal and chemical degeneration of the milled GFRP was studied using TG-FTIR, while the composition of the obtained volatile products was identified using Py-GC/MS. With regard to pyrolysis kinetic behaviour of GFRP, the activation energy (Ea) of whole pyrolysis treatment was determined using Kissinger model, while linear and nonlinear isoconversional models were employed to calculate Ea for each conversion phase. Finally, the kinetic methods of distributed activation energy and the independent parallel reactions were employed to fit TG-DTG experimental data. The results revealed that the GFRP is rich in volatile content (49%), while TG-FTIR analysis showed that C–H, CO, N–O, C–O–C were the main functional groups in the formulated volatile products. Meanwhile, GC/MS measurements showed that methacrylic acid (at 5 °C/min) and 2-Butenoic acid, methyl ester, (Z) (at 10–30 °C/min) were the major compounds in the obtained volatile products with abundance of 92% and 88%, respectively. Meanwhile, the kinetic study showed that Ea was estimated at 200 KJ/mol (Kissinger), 143–184 KJ/mol (linear models), and 153–157 KJ/mol (nonlinear model) with R2 in the range of 92–96.Samy YousefJustas EimontasNerijus StriūgasSharath P. SubadraMohammed Ali AbdelnabyElsevierarticleGlass fibre-reinforced polymersThermoplastic resinPyrolysis treatmentPoly(methyl methacrylate)-PMMAPyrolysis kineticsMining engineering. MetallurgyTN1-997ENJournal of Materials Research and Technology, Vol 15, Iss , Pp 5360-5374 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Glass fibre-reinforced polymers Thermoplastic resin Pyrolysis treatment Poly(methyl methacrylate)-PMMA Pyrolysis kinetics Mining engineering. Metallurgy TN1-997
spellingShingle	Glass fibre-reinforced polymers Thermoplastic resin Pyrolysis treatment Poly(methyl methacrylate)-PMMA Pyrolysis kinetics Mining engineering. Metallurgy TN1-997 Samy Yousef Justas Eimontas Nerijus Striūgas Sharath P. Subadra Mohammed Ali Abdelnaby Thermal degradation and pyrolysis kinetic behaviour of glass fibre-reinforced thermoplastic resin by TG-FTIR, Py-GC/MS, linear and nonlinear isoconversional models
description	Recently, global demand for glass fibre-reinforced thermoplastic (GFRP) composites and their applications in the production of wind turbine blades has increased due to their bigger strength, impact resistance, toughness, etc. compared to thermosetting resin. In this work, the thermal degradation and pyrolysis kinetic behaviour of GFRP were studied using TG-FTIR, Py-GC/MS, linear and nonlinear isoconversional models to investigate potential applications in the use of pyrolysis technology in end-of-life GFRP treatment. The experiments were carried out on milled glass fibre/poly(methyl methacrylate)-PMMA composites prepared using the vacuum-assisted resin transfer method and the grinding process. The morphological, ultimate, and proximate properties of the feedstock were observed. The thermal and chemical degeneration of the milled GFRP was studied using TG-FTIR, while the composition of the obtained volatile products was identified using Py-GC/MS. With regard to pyrolysis kinetic behaviour of GFRP, the activation energy (Ea) of whole pyrolysis treatment was determined using Kissinger model, while linear and nonlinear isoconversional models were employed to calculate Ea for each conversion phase. Finally, the kinetic methods of distributed activation energy and the independent parallel reactions were employed to fit TG-DTG experimental data. The results revealed that the GFRP is rich in volatile content (49%), while TG-FTIR analysis showed that C–H, CO, N–O, C–O–C were the main functional groups in the formulated volatile products. Meanwhile, GC/MS measurements showed that methacrylic acid (at 5 °C/min) and 2-Butenoic acid, methyl ester, (Z) (at 10–30 °C/min) were the major compounds in the obtained volatile products with abundance of 92% and 88%, respectively. Meanwhile, the kinetic study showed that Ea was estimated at 200 KJ/mol (Kissinger), 143–184 KJ/mol (linear models), and 153–157 KJ/mol (nonlinear model) with R2 in the range of 92–96.
format	article
author	Samy Yousef Justas Eimontas Nerijus Striūgas Sharath P. Subadra Mohammed Ali Abdelnaby
author_facet	Samy Yousef Justas Eimontas Nerijus Striūgas Sharath P. Subadra Mohammed Ali Abdelnaby
author_sort	Samy Yousef
title	Thermal degradation and pyrolysis kinetic behaviour of glass fibre-reinforced thermoplastic resin by TG-FTIR, Py-GC/MS, linear and nonlinear isoconversional models
title_short	Thermal degradation and pyrolysis kinetic behaviour of glass fibre-reinforced thermoplastic resin by TG-FTIR, Py-GC/MS, linear and nonlinear isoconversional models
title_full	Thermal degradation and pyrolysis kinetic behaviour of glass fibre-reinforced thermoplastic resin by TG-FTIR, Py-GC/MS, linear and nonlinear isoconversional models
title_fullStr	Thermal degradation and pyrolysis kinetic behaviour of glass fibre-reinforced thermoplastic resin by TG-FTIR, Py-GC/MS, linear and nonlinear isoconversional models
title_full_unstemmed	Thermal degradation and pyrolysis kinetic behaviour of glass fibre-reinforced thermoplastic resin by TG-FTIR, Py-GC/MS, linear and nonlinear isoconversional models
title_sort	thermal degradation and pyrolysis kinetic behaviour of glass fibre-reinforced thermoplastic resin by tg-ftir, py-gc/ms, linear and nonlinear isoconversional models
publisher	Elsevier
publishDate	2021
url	https://doaj.org/article/ca26c49f78344d599ce94acaf3746a89
work_keys_str_mv	AT samyyousef thermaldegradationandpyrolysiskineticbehaviourofglassfibrereinforcedthermoplasticresinbytgftirpygcmslinearandnonlinearisoconversionalmodels AT justaseimontas thermaldegradationandpyrolysiskineticbehaviourofglassfibrereinforcedthermoplasticresinbytgftirpygcmslinearandnonlinearisoconversionalmodels AT nerijusstriugas thermaldegradationandpyrolysiskineticbehaviourofglassfibrereinforcedthermoplasticresinbytgftirpygcmslinearandnonlinearisoconversionalmodels AT sharathpsubadra thermaldegradationandpyrolysiskineticbehaviourofglassfibrereinforcedthermoplasticresinbytgftirpygcmslinearandnonlinearisoconversionalmodels AT mohammedaliabdelnaby thermaldegradationandpyrolysiskineticbehaviourofglassfibrereinforcedthermoplasticresinbytgftirpygcmslinearandnonlinearisoconversionalmodels
_version_	1718419622913376256

Thermal degradation and pyrolysis kinetic behaviour of glass fibre-reinforced thermoplastic resin by TG-FTIR, Py-GC/MS, linear and nonlinear isoconversional models

Ejemplares similares