Investigations on the Influence of Annealing on Microstructure and Mechanical Properties of Electrodeposited Ni-Mo and Ni-Mo-W Alloy Coatings

Ni-Mo and Ni-Mo-W coatings were electrodeposited on a stainless steel sheet, and then were annealed at 200, 400, and 600 °C. The effect of annealing heat treatment on the microstructure of Ni-Mo and Ni-Mo-W electrodepositions, their nano-hardness, and tribological properties were investigated. It wa...

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Autores principales: Chao Zhang, Wudong Si, Yin Wang, Sichao Dai, Da Shu
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Publicado: MDPI AG 2021
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spelling oai:doaj.org-article:ca2b3890f41a49d383b680f383225ebc2021-11-25T17:17:05ZInvestigations on the Influence of Annealing on Microstructure and Mechanical Properties of Electrodeposited Ni-Mo and Ni-Mo-W Alloy Coatings10.3390/coatings111114282079-6412https://doaj.org/article/ca2b3890f41a49d383b680f383225ebc2021-11-01T00:00:00Zhttps://www.mdpi.com/2079-6412/11/11/1428https://doaj.org/toc/2079-6412Ni-Mo and Ni-Mo-W coatings were electrodeposited on a stainless steel sheet, and then were annealed at 200, 400, and 600 °C. The effect of annealing heat treatment on the microstructure of Ni-Mo and Ni-Mo-W electrodepositions, their nano-hardness, and tribological properties were investigated. It was revealed that the average crystalline are refined and phase separation are promoted with formation of Mo-W related intermetallic precipitates at temperature exceed 400 °C on account of the co-existence of Mo-W elements within Ni-Mo-W coatings. Annealing heat treatment leads to hardening, and the hardness and elastic module increase significantly. The grain boundary (GB) relaxation and hard precipitated intermetallic particles are responsible for the annealing-induced hardening for ≤400 °C annealed and 600 °C annealed Ni-Mo-W coatings, respectively. In addition, both adhesive wear and abrasive wear are observed for coatings, and abrasive wear becomes predominant when annealing temperature up to 600 °C. The wear resistance of coatings is improved eventually by formation of a mixture of lubricated oxides upon annealing at 600 °C and the enhancement of <i>H/E</i> ratio for ≤400 °C annealed Ni-Mo-W coatings.Chao ZhangWudong SiYin WangSichao DaiDa ShuMDPI AGarticleelectrodepositionNi-Mo-W coatingsannealingmicrostructuremechanical propertiesEngineering (General). Civil engineering (General)TA1-2040ENCoatings, Vol 11, Iss 1428, p 1428 (2021)
institution DOAJ
collection DOAJ
language EN
topic electrodeposition
Ni-Mo-W coatings
annealing
microstructure
mechanical properties
Engineering (General). Civil engineering (General)
TA1-2040
spellingShingle electrodeposition
Ni-Mo-W coatings
annealing
microstructure
mechanical properties
Engineering (General). Civil engineering (General)
TA1-2040
Chao Zhang
Wudong Si
Yin Wang
Sichao Dai
Da Shu
Investigations on the Influence of Annealing on Microstructure and Mechanical Properties of Electrodeposited Ni-Mo and Ni-Mo-W Alloy Coatings
description Ni-Mo and Ni-Mo-W coatings were electrodeposited on a stainless steel sheet, and then were annealed at 200, 400, and 600 °C. The effect of annealing heat treatment on the microstructure of Ni-Mo and Ni-Mo-W electrodepositions, their nano-hardness, and tribological properties were investigated. It was revealed that the average crystalline are refined and phase separation are promoted with formation of Mo-W related intermetallic precipitates at temperature exceed 400 °C on account of the co-existence of Mo-W elements within Ni-Mo-W coatings. Annealing heat treatment leads to hardening, and the hardness and elastic module increase significantly. The grain boundary (GB) relaxation and hard precipitated intermetallic particles are responsible for the annealing-induced hardening for ≤400 °C annealed and 600 °C annealed Ni-Mo-W coatings, respectively. In addition, both adhesive wear and abrasive wear are observed for coatings, and abrasive wear becomes predominant when annealing temperature up to 600 °C. The wear resistance of coatings is improved eventually by formation of a mixture of lubricated oxides upon annealing at 600 °C and the enhancement of <i>H/E</i> ratio for ≤400 °C annealed Ni-Mo-W coatings.
format article
author Chao Zhang
Wudong Si
Yin Wang
Sichao Dai
Da Shu
author_facet Chao Zhang
Wudong Si
Yin Wang
Sichao Dai
Da Shu
author_sort Chao Zhang
title Investigations on the Influence of Annealing on Microstructure and Mechanical Properties of Electrodeposited Ni-Mo and Ni-Mo-W Alloy Coatings
title_short Investigations on the Influence of Annealing on Microstructure and Mechanical Properties of Electrodeposited Ni-Mo and Ni-Mo-W Alloy Coatings
title_full Investigations on the Influence of Annealing on Microstructure and Mechanical Properties of Electrodeposited Ni-Mo and Ni-Mo-W Alloy Coatings
title_fullStr Investigations on the Influence of Annealing on Microstructure and Mechanical Properties of Electrodeposited Ni-Mo and Ni-Mo-W Alloy Coatings
title_full_unstemmed Investigations on the Influence of Annealing on Microstructure and Mechanical Properties of Electrodeposited Ni-Mo and Ni-Mo-W Alloy Coatings
title_sort investigations on the influence of annealing on microstructure and mechanical properties of electrodeposited ni-mo and ni-mo-w alloy coatings
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/ca2b3890f41a49d383b680f383225ebc
work_keys_str_mv AT chaozhang investigationsontheinfluenceofannealingonmicrostructureandmechanicalpropertiesofelectrodepositednimoandnimowalloycoatings
AT wudongsi investigationsontheinfluenceofannealingonmicrostructureandmechanicalpropertiesofelectrodepositednimoandnimowalloycoatings
AT yinwang investigationsontheinfluenceofannealingonmicrostructureandmechanicalpropertiesofelectrodepositednimoandnimowalloycoatings
AT sichaodai investigationsontheinfluenceofannealingonmicrostructureandmechanicalpropertiesofelectrodepositednimoandnimowalloycoatings
AT dashu investigationsontheinfluenceofannealingonmicrostructureandmechanicalpropertiesofelectrodepositednimoandnimowalloycoatings
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