Tuning organic crystal chirality by the molar masses of tailored polymeric additives
Hierarchically ordered chiral crystals have attracted intense research efforts but the need of enantiomeric pure building blocks and difficulties in the precise control of chirality transfer poses a barrier to their application. Here, the authors describe a process which allows preferred formation o...
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Nature Portfolio
2021
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oai:doaj.org-article:ca6335fafccf4294a8b9308a94b613fa2021-11-28T12:31:39ZTuning organic crystal chirality by the molar masses of tailored polymeric additives10.1038/s41467-021-27236-12041-1723https://doaj.org/article/ca6335fafccf4294a8b9308a94b613fa2021-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-27236-1https://doaj.org/toc/2041-1723Hierarchically ordered chiral crystals have attracted intense research efforts but the need of enantiomeric pure building blocks and difficulties in the precise control of chirality transfer poses a barrier to their application. Here, the authors describe a process which allows preferred formation of one enantiomorph from a racemic solution and the specific oriented attachment of this enantiomorph by balancing stereoselective and non stereoselective interactions.Xichong YeBowen LiZhaoxu WangJing LiJie ZhangXinhua WanNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-9 (2021) |
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Science Q Xichong Ye Bowen Li Zhaoxu Wang Jing Li Jie Zhang Xinhua Wan Tuning organic crystal chirality by the molar masses of tailored polymeric additives |
description |
Hierarchically ordered chiral crystals have attracted intense research efforts but the need of enantiomeric pure building blocks and difficulties in the precise control of chirality transfer poses a barrier to their application. Here, the authors describe a process which allows preferred formation of one enantiomorph from a racemic solution and the specific oriented attachment of this enantiomorph by balancing stereoselective and non stereoselective interactions. |
format |
article |
author |
Xichong Ye Bowen Li Zhaoxu Wang Jing Li Jie Zhang Xinhua Wan |
author_facet |
Xichong Ye Bowen Li Zhaoxu Wang Jing Li Jie Zhang Xinhua Wan |
author_sort |
Xichong Ye |
title |
Tuning organic crystal chirality by the molar masses of tailored polymeric additives |
title_short |
Tuning organic crystal chirality by the molar masses of tailored polymeric additives |
title_full |
Tuning organic crystal chirality by the molar masses of tailored polymeric additives |
title_fullStr |
Tuning organic crystal chirality by the molar masses of tailored polymeric additives |
title_full_unstemmed |
Tuning organic crystal chirality by the molar masses of tailored polymeric additives |
title_sort |
tuning organic crystal chirality by the molar masses of tailored polymeric additives |
publisher |
Nature Portfolio |
publishDate |
2021 |
url |
https://doaj.org/article/ca6335fafccf4294a8b9308a94b613fa |
work_keys_str_mv |
AT xichongye tuningorganiccrystalchiralitybythemolarmassesoftailoredpolymericadditives AT bowenli tuningorganiccrystalchiralitybythemolarmassesoftailoredpolymericadditives AT zhaoxuwang tuningorganiccrystalchiralitybythemolarmassesoftailoredpolymericadditives AT jingli tuningorganiccrystalchiralitybythemolarmassesoftailoredpolymericadditives AT jiezhang tuningorganiccrystalchiralitybythemolarmassesoftailoredpolymericadditives AT xinhuawan tuningorganiccrystalchiralitybythemolarmassesoftailoredpolymericadditives |
_version_ |
1718407920240033792 |