Tuning organic crystal chirality by the molar masses of tailored polymeric additives

Hierarchically ordered chiral crystals have attracted intense research efforts but the need of enantiomeric pure building blocks and difficulties in the precise control of chirality transfer poses a barrier to their application. Here, the authors describe a process which allows preferred formation o...

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Autores principales: Xichong Ye, Bowen Li, Zhaoxu Wang, Jing Li, Jie Zhang, Xinhua Wan
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Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/ca6335fafccf4294a8b9308a94b613fa
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spelling oai:doaj.org-article:ca6335fafccf4294a8b9308a94b613fa2021-11-28T12:31:39ZTuning organic crystal chirality by the molar masses of tailored polymeric additives10.1038/s41467-021-27236-12041-1723https://doaj.org/article/ca6335fafccf4294a8b9308a94b613fa2021-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-27236-1https://doaj.org/toc/2041-1723Hierarchically ordered chiral crystals have attracted intense research efforts but the need of enantiomeric pure building blocks and difficulties in the precise control of chirality transfer poses a barrier to their application. Here, the authors describe a process which allows preferred formation of one enantiomorph from a racemic solution and the specific oriented attachment of this enantiomorph by balancing stereoselective and non stereoselective interactions.Xichong YeBowen LiZhaoxu WangJing LiJie ZhangXinhua WanNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-9 (2021)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Xichong Ye
Bowen Li
Zhaoxu Wang
Jing Li
Jie Zhang
Xinhua Wan
Tuning organic crystal chirality by the molar masses of tailored polymeric additives
description Hierarchically ordered chiral crystals have attracted intense research efforts but the need of enantiomeric pure building blocks and difficulties in the precise control of chirality transfer poses a barrier to their application. Here, the authors describe a process which allows preferred formation of one enantiomorph from a racemic solution and the specific oriented attachment of this enantiomorph by balancing stereoselective and non stereoselective interactions.
format article
author Xichong Ye
Bowen Li
Zhaoxu Wang
Jing Li
Jie Zhang
Xinhua Wan
author_facet Xichong Ye
Bowen Li
Zhaoxu Wang
Jing Li
Jie Zhang
Xinhua Wan
author_sort Xichong Ye
title Tuning organic crystal chirality by the molar masses of tailored polymeric additives
title_short Tuning organic crystal chirality by the molar masses of tailored polymeric additives
title_full Tuning organic crystal chirality by the molar masses of tailored polymeric additives
title_fullStr Tuning organic crystal chirality by the molar masses of tailored polymeric additives
title_full_unstemmed Tuning organic crystal chirality by the molar masses of tailored polymeric additives
title_sort tuning organic crystal chirality by the molar masses of tailored polymeric additives
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/ca6335fafccf4294a8b9308a94b613fa
work_keys_str_mv AT xichongye tuningorganiccrystalchiralitybythemolarmassesoftailoredpolymericadditives
AT bowenli tuningorganiccrystalchiralitybythemolarmassesoftailoredpolymericadditives
AT zhaoxuwang tuningorganiccrystalchiralitybythemolarmassesoftailoredpolymericadditives
AT jingli tuningorganiccrystalchiralitybythemolarmassesoftailoredpolymericadditives
AT jiezhang tuningorganiccrystalchiralitybythemolarmassesoftailoredpolymericadditives
AT xinhuawan tuningorganiccrystalchiralitybythemolarmassesoftailoredpolymericadditives
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