Stacked antiaromatic porphyrins

It has been proposed that stacking antiaromatic molecules can build three-dimensional aromaticity, but this claim has lacked experimental validation. Here the authors report that π–π stacked antiaromatic porphyrins display significantly reduced antiaromaticity in solid state and in solution.

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Autores principales:	Ryo Nozawa, Hiroko Tanaka, Won-Young Cha, Yongseok Hong, Ichiro Hisaki, Soji Shimizu, Ji-Young Shin, Tim Kowalczyk, Stephan Irle, Dongho Kim, Hiroshi Shinokubo
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2016
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/ca9d341f38b34cc1989b17ac2caceaa4
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

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spelling	oai:doaj.org-article:ca9d341f38b34cc1989b17ac2caceaa42021-12-02T15:34:50ZStacked antiaromatic porphyrins10.1038/ncomms136202041-1723https://doaj.org/article/ca9d341f38b34cc1989b17ac2caceaa42016-11-01T00:00:00Zhttps://doi.org/10.1038/ncomms13620https://doaj.org/toc/2041-1723It has been proposed that stacking antiaromatic molecules can build three-dimensional aromaticity, but this claim has lacked experimental validation. Here the authors report that π–π stacked antiaromatic porphyrins display significantly reduced antiaromaticity in solid state and in solution.Ryo NozawaHiroko TanakaWon-Young ChaYongseok HongIchiro HisakiSoji ShimizuJi-Young ShinTim KowalczykStephan IrleDongho KimHiroshi ShinokuboNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-7 (2016)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Ryo Nozawa Hiroko Tanaka Won-Young Cha Yongseok Hong Ichiro Hisaki Soji Shimizu Ji-Young Shin Tim Kowalczyk Stephan Irle Dongho Kim Hiroshi Shinokubo Stacked antiaromatic porphyrins
description	It has been proposed that stacking antiaromatic molecules can build three-dimensional aromaticity, but this claim has lacked experimental validation. Here the authors report that π–π stacked antiaromatic porphyrins display significantly reduced antiaromaticity in solid state and in solution.
format	article
author	Ryo Nozawa Hiroko Tanaka Won-Young Cha Yongseok Hong Ichiro Hisaki Soji Shimizu Ji-Young Shin Tim Kowalczyk Stephan Irle Dongho Kim Hiroshi Shinokubo
author_facet	Ryo Nozawa Hiroko Tanaka Won-Young Cha Yongseok Hong Ichiro Hisaki Soji Shimizu Ji-Young Shin Tim Kowalczyk Stephan Irle Dongho Kim Hiroshi Shinokubo
author_sort	Ryo Nozawa
title	Stacked antiaromatic porphyrins
title_short	Stacked antiaromatic porphyrins
title_full	Stacked antiaromatic porphyrins
title_fullStr	Stacked antiaromatic porphyrins
title_full_unstemmed	Stacked antiaromatic porphyrins
title_sort	stacked antiaromatic porphyrins
publisher	Nature Portfolio
publishDate	2016
url	https://doaj.org/article/ca9d341f38b34cc1989b17ac2caceaa4
work_keys_str_mv	AT ryonozawa stackedantiaromaticporphyrins AT hirokotanaka stackedantiaromaticporphyrins AT wonyoungcha stackedantiaromaticporphyrins AT yongseokhong stackedantiaromaticporphyrins AT ichirohisaki stackedantiaromaticporphyrins AT sojishimizu stackedantiaromaticporphyrins AT jiyoungshin stackedantiaromaticporphyrins AT timkowalczyk stackedantiaromaticporphyrins AT stephanirle stackedantiaromaticporphyrins AT donghokim stackedantiaromaticporphyrins AT hiroshishinokubo stackedantiaromaticporphyrins
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Stacked antiaromatic porphyrins

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