Enantioselective [3+3] atroposelective annulation catalyzed by N-heterocyclic carbenes

Axially chiral compounds are commonly found in nature. Here, the authors show the highly enantioselective construction of axially chiral biaryls via an N-heterocyclic carbenes-catalyzed [3+3] atroposelective annulation of ynals with cyclic 1,3-diones.

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Autores principales:	Changgui Zhao, Donghui Guo, Kristin Munkerup, Kuo-Wei Huang, Fangyi Li, Jian Wang
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/caca689026b84ad7bafd64c9ed7fd5d3
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spelling	oai:doaj.org-article:caca689026b84ad7bafd64c9ed7fd5d32021-12-02T15:34:40ZEnantioselective [3+3] atroposelective annulation catalyzed by N-heterocyclic carbenes10.1038/s41467-018-02952-32041-1723https://doaj.org/article/caca689026b84ad7bafd64c9ed7fd5d32018-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-02952-3https://doaj.org/toc/2041-1723Axially chiral compounds are commonly found in nature. Here, the authors show the highly enantioselective construction of axially chiral biaryls via an N-heterocyclic carbenes-catalyzed [3+3] atroposelective annulation of ynals with cyclic 1,3-diones.Changgui ZhaoDonghui GuoKristin MunkerupKuo-Wei HuangFangyi LiJian WangNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-10 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Changgui Zhao Donghui Guo Kristin Munkerup Kuo-Wei Huang Fangyi Li Jian Wang Enantioselective [3+3] atroposelective annulation catalyzed by N-heterocyclic carbenes
description	Axially chiral compounds are commonly found in nature. Here, the authors show the highly enantioselective construction of axially chiral biaryls via an N-heterocyclic carbenes-catalyzed [3+3] atroposelective annulation of ynals with cyclic 1,3-diones.
format	article
author	Changgui Zhao Donghui Guo Kristin Munkerup Kuo-Wei Huang Fangyi Li Jian Wang
author_facet	Changgui Zhao Donghui Guo Kristin Munkerup Kuo-Wei Huang Fangyi Li Jian Wang
author_sort	Changgui Zhao
title	Enantioselective [3+3] atroposelective annulation catalyzed by N-heterocyclic carbenes
title_short	Enantioselective [3+3] atroposelective annulation catalyzed by N-heterocyclic carbenes
title_full	Enantioselective [3+3] atroposelective annulation catalyzed by N-heterocyclic carbenes
title_fullStr	Enantioselective [3+3] atroposelective annulation catalyzed by N-heterocyclic carbenes
title_full_unstemmed	Enantioselective [3+3] atroposelective annulation catalyzed by N-heterocyclic carbenes
title_sort	enantioselective [3+3] atroposelective annulation catalyzed by n-heterocyclic carbenes
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/caca689026b84ad7bafd64c9ed7fd5d3
work_keys_str_mv	AT changguizhao enantioselective33atroposelectiveannulationcatalyzedbynheterocycliccarbenes AT donghuiguo enantioselective33atroposelectiveannulationcatalyzedbynheterocycliccarbenes AT kristinmunkerup enantioselective33atroposelectiveannulationcatalyzedbynheterocycliccarbenes AT kuoweihuang enantioselective33atroposelectiveannulationcatalyzedbynheterocycliccarbenes AT fangyili enantioselective33atroposelectiveannulationcatalyzedbynheterocycliccarbenes AT jianwang enantioselective33atroposelectiveannulationcatalyzedbynheterocycliccarbenes
_version_	1718386806944169984

Enantioselective [3+3] atroposelective annulation catalyzed by N-heterocyclic carbenes

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